From 1dbd2aaa696169f4a54de92e7462c405d4011367 Mon Sep 17 00:00:00 2001 From: dalito Date: Thu, 10 Aug 2023 20:35:15 +0000 Subject: [PATCH] deploy: fe83876a97e60267ede1676777de1a0ec88ebd15 --- .nojekyll | 0 README.md | 3 + voc4cat.log | 16 + voc4cat.ttl | 1960 ++++++++++++++++++ voc4cat.xlsx | Bin 0 -> 93216 bytes voc4cat/index.html | 4952 ++++++++++++++++++++++++++++++++++++++++++++ 6 files changed, 6931 insertions(+) create mode 100644 .nojekyll create mode 100644 README.md create mode 100644 voc4cat.log create mode 100644 voc4cat.ttl create mode 100644 voc4cat.xlsx create mode 100644 voc4cat/index.html diff --git a/.nojekyll b/.nojekyll new file mode 100644 index 0000000..e69de29 diff --git a/README.md b/README.md new file mode 100644 index 0000000..5bddb0f --- /dev/null +++ b/README.md @@ -0,0 +1,3 @@ +**Directory to collect the vocabularies in rdf/turtle format** + +that were created using the voc4cat workflow and its CI/CD pipeline. diff --git a/voc4cat.log b/voc4cat.log new file mode 100644 index 0000000..8287189 --- /dev/null +++ b/voc4cat.log @@ -0,0 +1,16 @@ +2023-08-10 20:35:11|voc4cat.cli |INFO |Executing cmd: voc4cat transform --logfile publish/voc4cat.log --join publish/ +2023-08-10 20:35:11|voc4cat.cli |DEBUG |Processing common options. +2023-08-10 20:35:11|voc4cat.transform |DEBUG |Transform subcommand started! +2023-08-10 20:35:11|voc4cat.transform |DEBUG |Processing "publish/voc4cat.ttl" +2023-08-10 20:35:11|voc4cat.transform |DEBUG |-> nothing to do for rdf files! +2023-08-10 20:35:11|voc4cat.cli |INFO |Executing cmd: voc4cat docs --force --logfile publish/voc4cat.log publish/ +2023-08-10 20:35:11|voc4cat.cli |DEBUG |Processing common options. +2023-08-10 20:35:11|voc4cat.docs |DEBUG |Docs subcommand started! +2023-08-10 20:35:11|voc4cat.docs |DEBUG |Processing "publish/voc4cat.ttl" +2023-08-10 20:35:11|pylode.common |DEBUG |Application dir: /opt/hostedtoolcache/Python/3.11.4/x64/lib/python3.11/site-packages/pylode +2023-08-10 20:35:13|voc4cat.docs |INFO |-> built pyLODE documentation for publish/voc4cat.ttl +2023-08-10 20:35:14|voc4cat.cli |INFO |Executing cmd: voc4cat convert --logfile publish/voc4cat.log --template templates/voc4cat_template_043.xlsx publish/ +2023-08-10 20:35:14|voc4cat.cli |DEBUG |Processing common options. +2023-08-10 20:35:14|voc4cat.convert |DEBUG |Convert subcommand started! +2023-08-10 20:35:14|voc4cat.convert |DEBUG |Processing "publish/voc4cat.ttl" +2023-08-10 20:35:14|voc4cat.convert |INFO |-> successfully converted to publish/voc4cat.xlsx diff --git a/voc4cat.ttl b/voc4cat.ttl new file mode 100644 index 0000000..b471fa1 --- /dev/null +++ b/voc4cat.ttl @@ -0,0 +1,1960 @@ +@prefix cs: . +@prefix dcat: . +@prefix dcterms: . +@prefix owl: . +@prefix skos: . +@prefix xsd: . + +cs:0000005 a skos:Concept ; + dcterms:identifier "voc4cat_0000005"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000004 ; + skos:definition "A chemical compound formed by the reaction of a metal with oxygen."@en ; + skos:inScheme cs: ; + skos:prefLabel "metal oxide"@en . + +cs:0000007 a skos:Concept ; + dcterms:identifier "voc4cat_0000007"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "EF"@en ; + skos:broader cs:0000006 ; + skos:definition "The energy level in a semiconductor where the probability of finding an electron is 0.5. "@en ; + skos:inScheme cs: ; + skos:prefLabel "Fermi level"@en . + +cs:0000008 a skos:Concept ; + dcterms:identifier "voc4cat_0000008"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000006 ; + skos:definition "The degree of a three-dimensional structural order of atoms which constitute the crystal lattice of a material."@en ; + skos:inScheme cs: ; + skos:prefLabel "crystallinity"@en . + +cs:0000009 a skos:Concept ; + dcterms:identifier "voc4cat_0000009"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000006 ; + skos:definition "Pore size distribution refers to the range of pore sizes in a material. "@en ; + skos:inScheme cs: ; + skos:prefLabel "pore size distribution"@en . + +cs:0000010 a skos:Concept ; + dcterms:identifier "voc4cat_0000010"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "energy bandgap; Eg"@en ; + skos:broader cs:0000006 ; + skos:definition "The energy difference between a semiconductor’s valence band top and conduction band bottom, which is required to excite an electron from the former to the latter. "@en ; + skos:inScheme cs: ; + skos:prefLabel "bandgap energy"@en . + +cs:0000011 a skos:Concept ; + dcterms:identifier "voc4cat_0000011"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "VB"@en ; + skos:broader cs:0000006 ; + skos:definition "The band of energy levels in a solid fully occupied by electrons at 0 K (273.15 °C)."@en ; + skos:inScheme cs: ; + skos:prefLabel "valence band"@en . + +cs:0000012 a skos:Concept ; + dcterms:identifier "voc4cat_0000012"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "CB"@en ; + skos:broader cs:0000006 ; + skos:definition "The energy band of electronic levels of partially or fully filled mobile electrons in a metal or a semiconductor. "@en ; + skos:inScheme cs: ; + skos:prefLabel "conduction band"@en . + +cs:0000013 a skos:Concept ; + dcterms:identifier "voc4cat_0000013"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "SSA"@en ; + skos:broader cs:0000006 ; + skos:definition "Α measure of the total surface area of a material per unit mass or volume."@en ; + skos:inScheme cs: ; + skos:prefLabel "specific surface area"@en . + +cs:0000015 a skos:Concept ; + dcterms:identifier "voc4cat_0000015"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000014 ; + skos:definition "The introduction of foreign atoms into a semiconductor leading to the formation of new energy levels and charge concentrations."@en ; + skos:inScheme cs: ; + skos:prefLabel "doping"@en . + +cs:0000018 a skos:Concept ; + dcterms:identifier "voc4cat_0000018"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000017 ; + skos:definition "Mass of a powdered photocatalyst used for an experiment."@en ; + skos:inScheme cs: ; + skos:prefLabel "powder mass"@en . + +cs:0000021 a skos:Concept ; + dcterms:identifier "voc4cat_0000021"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "spray-coating"@en ; + skos:broader cs:0000020 ; + skos:definition "A technique used to deposit uniform thin films onto a substrate by spraying a solution of the material onto the surface."@en ; + skos:inScheme cs: ; + skos:prefLabel "spray coating"@en . + +cs:0000022 a skos:Concept ; + dcterms:identifier "voc4cat_0000022"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000020 ; + skos:definition "A tape-casting method used to deposit thin films of a photocatalyst onto the surface of a substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "doctor blading"@en . + +cs:0000023 a skos:Concept ; + dcterms:identifier "voc4cat_0000023"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "spin casting"@en, + "spin-casting"@en, + "spin-coating"@en ; + skos:broader cs:0000020 ; + skos:definition "A technique used to deposit uniform thin films onto a substrate (e.g., metal or glass) by spinning at high speeds a solution (paste) of the material onto the surface."@en ; + skos:inScheme cs: ; + skos:prefLabel "spin coating"@en . + +cs:0000026 a skos:Concept ; + dcterms:identifier "voc4cat_0000026"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000025 ; + skos:definition "A flat surface made of a metal (e.g., titanium, stainless steel) serving as a substrate for the deposition of a photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "metallic substrate"@en . + +cs:0000028 a skos:Concept ; + dcterms:identifier "voc4cat_0000028"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "FTO; FTO glass"@en ; + skos:broader cs:0000027 ; + skos:definition "Transparent conductive metal oxide (fluorine doped tin oxide) that can be used in the fabrication of transparent electrodes for thin films."@en ; + skos:inScheme cs: ; + skos:prefLabel "fluorine doped tin oxide coated glass"@en . + +cs:0000029 a skos:Concept ; + dcterms:identifier "voc4cat_0000029"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "ITO; ITO glass"@en ; + skos:broader cs:0000027 ; + skos:definition "Transparent conductive metal oxide (indium tin oxide) that can be used in the fabrication of transparent electrodes for thin films."@en ; + skos:inScheme cs: ; + skos:prefLabel "indium tin oxide coated glass"@en . + +cs:0000030 a skos:Concept ; + dcterms:identifier "voc4cat_0000030"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000027 ; + skos:definition "A resistant to thermal shock type of glass, composed mainly of silica and boron trioxide."@en ; + skos:inScheme cs: ; + skos:prefLabel "borosilicate glass"@en . + +cs:0000031 a skos:Concept ; + dcterms:identifier "voc4cat_0000031"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "quartz"@en ; + skos:broader cs:0000027 ; + skos:definition "A type of pure silicon dioxide, highly crystalline glass that allows the transmission of light in the UV wavelength range."@en ; + skos:inScheme cs: ; + skos:prefLabel "quartz glass"@en . + +cs:0000032 a skos:Concept ; + dcterms:identifier "voc4cat_0000032"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000025 ; + skos:definition "A surface made of a ceramic material (e.g., alumina) serving as a substrate for the deposition of a photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "ceramic substrate"@en . + +cs:0000034 a skos:Concept ; + dcterms:identifier "voc4cat_0000034"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000033 ; + skos:definition "The width of the substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "substrate width"@en . + +cs:0000035 a skos:Concept ; + dcterms:identifier "voc4cat_0000035"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000033 ; + skos:definition "The depth of the substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "substrate depth"@en . + +cs:0000036 a skos:Concept ; + dcterms:identifier "voc4cat_0000036"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000033 ; + skos:definition "The thickness of the substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "substrate thickness"@en . + +cs:0000037 a skos:Concept ; + dcterms:identifier "voc4cat_0000037"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "substrate surface area"@en ; + skos:broader cs:0000033 ; + skos:definition "The surface area of the substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "substrate area"@en . + +cs:0000039 a skos:Concept ; + dcterms:identifier "voc4cat_0000039"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000038 ; + skos:definition "Mass of catalyst deposited onto the surface of a substrate."@en ; + skos:inScheme cs: ; + skos:prefLabel "thin film mass"@en . + +cs:0000041 a skos:Concept ; + dcterms:identifier "voc4cat_0000041"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000040 ; + skos:definition "The width of the film of the deposited photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "thin film width"@en . + +cs:0000042 a skos:Concept ; + dcterms:identifier "voc4cat_0000042"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000040 ; + skos:definition "The thickness of the film of the deposited photocatalyst. "@en ; + skos:inScheme cs: ; + skos:prefLabel "thin film thickness"@en . + +cs:0000043 a skos:Concept ; + dcterms:identifier "voc4cat_0000043"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000040 ; + skos:definition "The depth of the film of the deposited photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "thin film depth"@en . + +cs:0000044 a skos:Concept ; + dcterms:identifier "voc4cat_0000044"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000040 ; + skos:definition "The area of the substrate covered by the deposited photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "thin film area"@en . + +cs:0000047 a skos:Concept ; + dcterms:identifier "voc4cat_0000047"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000046 ; + skos:definition "Filtering of literature research to include only the most relevant sources of information for the application / experiment / catalysts of interest."@en ; + skos:inScheme cs: ; + skos:prefLabel "literature collection"@en . + +cs:0000048 a skos:Concept ; + dcterms:identifier "voc4cat_0000048"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "literature organization; organization of literature; citation management software"@en ; + skos:broader cs:0000046 ; + skos:definition "Addition and organization of relevant literature of interest using a citation management software (e.g., Mendeley, Zotero, EndNote etc.) allowing for easy access and categorization."@en ; + skos:inScheme cs: ; + skos:prefLabel "literature organization"@en . + +cs:0000050 a skos:Concept ; + dcterms:identifier "voc4cat_0000050"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "Duration of each synthesis step needed to synthesize the desired photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "synthesis duration"@en . + +cs:0000051 a skos:Concept ; + dcterms:identifier "voc4cat_0000051"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "Temperature externally applied (if necessary) in any of the synthesis step. Higher temperature values can be observed if an exothermic reaction takes place during the synthesis."@en ; + skos:inScheme cs: ; + skos:prefLabel "synthesis temperature"@en . + +cs:0000052 a skos:Concept ; + dcterms:identifier "voc4cat_0000052"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "pH value in each of the synthesis steps"@en ; + skos:inScheme cs: ; + skos:prefLabel "synthesis pH"@en . + +cs:0000053 a skos:Concept ; + dcterms:identifier "voc4cat_0000053"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "Pressure applied (if necessary) in any of the synthesis step. Changes in the pressure may be observed if variations in the temperature of the reaction occur (e.g., exothermic reaction) "@en ; + skos:inScheme cs: ; + skos:prefLabel "synthesis pressure"@en . + +cs:0000055 a skos:Concept ; + dcterms:identifier "voc4cat_0000055"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "A gas flow under which the calcination step takes place (e,g,, Ar or synthetic air)"@en ; + skos:inScheme cs: ; + skos:prefLabel "gaseous environment in calcination"@en . + +cs:0000056 a skos:Concept ; + dcterms:identifier "voc4cat_0000056"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "The flow of gas (usually in ml min-1) used in the calcination steps during synthesis"@en ; + skos:inScheme cs: ; + skos:prefLabel "gas flow rate in calcination"@en . + +cs:0000057 a skos:Concept ; + dcterms:identifier "voc4cat_0000057"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "Initial temperature of the calcination step."@en ; + skos:inScheme cs: ; + skos:prefLabel "calcination initial temperature"@en . + +cs:0000058 a skos:Concept ; + dcterms:identifier "voc4cat_0000058"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "Final temperature of the calcination step."@en ; + skos:inScheme cs: ; + skos:prefLabel "calcination final temperature"@en . + +cs:0000059 a skos:Concept ; + dcterms:identifier "voc4cat_0000059"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "Rate of increasing or decreasing the temperature during the calcination step. Usually mentioned in K min-1."@en ; + skos:inScheme cs: ; + skos:prefLabel "calcination heating rate"@en . + +cs:0000060 a skos:Concept ; + dcterms:identifier "voc4cat_0000060"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000054 ; + skos:definition "Time (usually in h) for which a desired temperature is held."@en ; + skos:inScheme cs: ; + skos:prefLabel "calcination dwelling time"@en . + +cs:0000061 a skos:Concept ; + dcterms:identifier "voc4cat_0000061"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "Equipment used in each step of the synthesis of the photocatalysts. The equipment can incude (but not limited to): crucibles, pH meters, condensers, volumetric cylinders, centrifuges, test tubes, flasks, beakers, mechanical shakers, pipettes, syringes, magenetic stirrers, heating plates, fitlers, funnels and digital balances."@en ; + skos:inScheme cs: ; + skos:prefLabel "synthesis equipment"@en . + +cs:0000063 a skos:Concept ; + dcterms:identifier "voc4cat_0000063"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000062 ; + skos:definition "Mass of chemicals used for synthesis"@en ; + skos:inScheme cs: ; + skos:prefLabel "mass of chemical substance for synthesis"@en . + +cs:0000064 a skos:Concept ; + dcterms:identifier "voc4cat_0000064"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000062 ; + skos:definition "Volume of chemicals used for synthesis"@en ; + skos:inScheme cs: ; + skos:prefLabel "volume chemical substance for synthesis"@en . + +cs:0000065 a skos:Concept ; + dcterms:identifier "voc4cat_0000065"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000062 ; + skos:definition "Concentration of chemicals used for synthesis"@en ; + skos:inScheme cs: ; + skos:prefLabel "concentration chemical substance for synthesis"@en . + +cs:0000085 a skos:Concept ; + dcterms:identifier "voc4cat_0000085"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000084 ; + skos:definition "Τhe lowest energy state of a system. "@en ; + skos:inScheme cs: ; + skos:prefLabel "ground state"@en . + +cs:0000086 a skos:Concept ; + dcterms:identifier "voc4cat_0000086"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000084 ; + skos:definition "Τhe temporary state of a system with higher energy than its ground state caused by an external factor. "@en ; + skos:inScheme cs: ; + skos:prefLabel "excited state"@en . + +cs:0000088 a skos:Concept ; + dcterms:identifier "voc4cat_0000088"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The transfer of an electron initiated by the absorption of a photon of sufficient energy. "@en ; + skos:inScheme cs: ; + skos:prefLabel "photoinduced electron transfer"@en . + +cs:0000089 a skos:Concept ; + dcterms:identifier "voc4cat_0000089"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The transfer of a hole initiated by the absorption of a photon of sufficient energy. "@en ; + skos:inScheme cs: ; + skos:prefLabel "photoinduced hole transfer"@en . + +cs:0000090 a skos:Concept ; + dcterms:identifier "voc4cat_0000090"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "charge photogeneration; photogenerated charges; charge photo-generation; electron excitation; electron-hole pair;"@en ; + skos:broader cs:0000087 ; + skos:definition "The generation of electron - hole pairs in a semiconductor as a result of light absorption of sufficient energy to overcome the bandgap energy. Electrons (negative charge) get excited to the conduction band, while holes (positive charge) remain in the valence band. "@en ; + skos:inScheme cs: ; + skos:prefLabel "photoinduced charge generation"@en . + +cs:0000091 a skos:Concept ; + dcterms:identifier "voc4cat_0000091"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The process by which photogenerated charges (electrons and holes) in a semiconductor recombine, resulting in the dissipation of energy in the form of e.g., heat or light. "@en ; + skos:inScheme cs: ; + skos:prefLabel "charge recombination"@en . + +cs:0000092 a skos:Concept ; + dcterms:identifier "voc4cat_0000092"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "Absorption is the process in which energy (e.g., photons) or an absorbent (e.g., a gas) is taken up by an absorbate. "@en ; + skos:inScheme cs: ; + skos:prefLabel "absorption"@en . + +cs:0000093 a skos:Concept ; + dcterms:identifier "voc4cat_0000093"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The binding (strong or weak) of a pollutant or a reactant molecule on the surface of a photocatalyst which facilitates the performance of photocatalytic reactions."@en ; + skos:inScheme cs: ; + skos:prefLabel "adsorption"@en . + +cs:0000094 a skos:Concept ; + dcterms:identifier "voc4cat_0000094"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The process under which reactants, intermediates and products are released from the surface of the photocatalyst. Desoprtion can be faciliated by an increase in temparature or a change in the pH."@en ; + skos:inScheme cs: ; + skos:prefLabel "desorption"@en . + +cs:0000095 a skos:Concept ; + dcterms:identifier "voc4cat_0000095"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The process of separating positive and negative charges in a semiconductor, typically as a result of an external force, (e.g., photoexcitation). "@en ; + skos:inScheme cs: ; + skos:prefLabel "charge separation"@en . + +cs:0000096 a skos:Concept ; + dcterms:identifier "voc4cat_0000096"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "photo-excitation"@en ; + skos:broader cs:0000087 ; + skos:definition "The state caused by the transition of electrons from the valence band top to the conduction band bottom by absorption of photons of sufficient energy. "@en ; + skos:inScheme cs: ; + skos:prefLabel "photoexcitation"@en . + +cs:0000097 a skos:Concept ; + dcterms:identifier "voc4cat_0000097"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The loss of electrons or an increase in the oxidation state of a species. "@en ; + skos:inScheme cs: ; + skos:prefLabel "oxidation"@en . + +cs:0000099 a skos:Concept ; + dcterms:identifier "voc4cat_0000099"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "photocatalytic carbon dioxide reduction; CO2 photoreduction; carbon dioxide photoreduction; artificial photosynthesis"@en ; + skos:broader cs:0000098 ; + skos:definition "The light-driven reduction (conversion) of carbon dioxide (CO2) to hydrocarbons and / or platform chemicals in presence of water. The absorption of light and the adsorption of the reactants is performed by a photocatalyst (usually a metal oxide). "@en ; + skos:inScheme cs: ; + skos:prefLabel "photocatalytic CO2 reduction"@en . + +cs:0000102 a skos:Concept ; + dcterms:identifier "voc4cat_0000102"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000101 ; + skos:definition "Concentration of the reactants (e.g., CO2 and H2O) used in the photocatalytic CO2 reduction experiments"@en ; + skos:inScheme cs: ; + skos:prefLabel "reactant concentration"@en . + +cs:0000103 a skos:Concept ; + dcterms:identifier "voc4cat_0000103"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000101 ; + skos:definition "Purity of reactants (e.g., CO2, H2O, He) used in the photocatalytic CO2 reduction experiments. Purity is measure of the impurities contained in the reactants' supply. The highest purity reactants should be used to ensure the collection of reliable results. "@en ; + skos:inScheme cs: ; + skos:prefLabel "reactant purity"@en . + +cs:0000104 a skos:Concept ; + dcterms:identifier "voc4cat_0000104"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000101 ; + skos:definition "The rate of flow of reactants (often in ml per min) in the photoreactor. Flow rates are usually controlled by mass flow controllers (MFCs) "@en ; + skos:inScheme cs: ; + skos:prefLabel "reactant flow rate"@en . + +cs:0000106 a skos:Concept ; + dcterms:identifier "voc4cat_0000106"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000105 ; + skos:definition "A molecule that accepts electrons from photoexcited species in a redox reaction and is subsequently consumed or degraded."@en ; + skos:inScheme cs: ; + skos:prefLabel "sacrificial acceptor"@en . + +cs:0000107 a skos:Concept ; + dcterms:identifier "voc4cat_0000107"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000105 ; + skos:definition "A molecule that donates electrons from photoexcited species in a redox reaction and is subsequently consumed or degraded."@en ; + skos:inScheme cs: ; + skos:prefLabel "sacrificial donor"@en . + +cs:0000109 a skos:Concept ; + dcterms:identifier "voc4cat_0000109"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "continuous flow mode"@en, + "continuous-flow mode"@en, + "flow-mode"@en ; + skos:broader cs:0000108 ; + skos:definition " Under flow conditions, a continuous flow of reactants is supplied to the reaction chamber and the formed products are removed and identified by an appropriate technique."@en ; + skos:inScheme cs: ; + skos:prefLabel "flow mode"@en . + +cs:0000110 a skos:Concept ; + dcterms:identifier "voc4cat_0000110"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "batch-mode"@en ; + skos:broader cs:0000108 ; + skos:definition "Operation mode in which the reaction chamber is filled with the (reactant) gas(es) up to a certain pressure, and the photoreaction products acummulate over time."@en ; + skos:inScheme cs: ; + skos:prefLabel "batch mode"@en . + +cs:0000112 a skos:Concept ; + dcterms:identifier "voc4cat_0000112"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000111 ; + skos:definition "Time for which a gas is purged through the reaction chamber."@en ; + skos:inScheme cs: ; + skos:prefLabel "purging duration"@en . + +cs:0000113 a skos:Concept ; + dcterms:identifier "voc4cat_0000113"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000111 ; + skos:definition "The time in between the collection of two data points."@en ; + skos:inScheme cs: ; + skos:prefLabel "sampling interval"@en . + +cs:0000114 a skos:Concept ; + dcterms:identifier "voc4cat_0000114"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000111 ; + skos:definition "The total duration in which the photocatalyst was under irradiation by the selected light source. "@en ; + skos:inScheme cs: ; + skos:prefLabel "irradiation duration"@en . + +cs:0000116 a skos:Concept ; + dcterms:identifier "voc4cat_0000116"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000115 ; + skos:definition "The temperature at the initiaton of the experiment."@en ; + skos:inScheme cs: ; + skos:prefLabel "experiment initial temperature"@en . + +cs:0000117 a skos:Concept ; + dcterms:identifier "voc4cat_0000117"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000115 ; + skos:definition "The temperature at the end of the experiment."@en ; + skos:inScheme cs: ; + skos:prefLabel "experiment final temperature"@en . + +cs:0000119 a skos:Concept ; + dcterms:identifier "voc4cat_0000119"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000118 ; + skos:definition "The pressure at the initiaton of the experiment or before a sampling event."@en ; + skos:inScheme cs: ; + skos:prefLabel "experiment initial pressure"@en . + +cs:0000120 a skos:Concept ; + dcterms:identifier "voc4cat_0000120"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000118 ; + skos:definition "The pressure at the end of the experiment or after a sampling event."@en ; + skos:inScheme cs: ; + skos:prefLabel "experiment final pressure"@en . + +cs:0000121 a skos:Concept ; + dcterms:identifier "voc4cat_0000121"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "The pressure drop occuring when collecting a gaseous sample for the reaction chamber. This pressure drop should be taken into consideration when caluclation the concentration of formed products. "@en ; + skos:inScheme cs: ; + skos:prefLabel "experiment pressure drop"@en . + +cs:0000122 a skos:Concept ; + dcterms:identifier "voc4cat_0000122"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "Pretreatment of the photocatalyst before its intoduction to the reaction chamber."@en ; + skos:inScheme cs: ; + skos:prefLabel "sample pre-treatment"@en . + +cs:0000123 a skos:Concept ; + dcterms:identifier "voc4cat_0000123"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "control experiment"@en ; + skos:broader cs:0000100 ; + skos:definition "Measurements performed to ensure that the studied photocatalytic reaction occurs because of the interaction of the photocatalyst with the reactants, and not from the environment or the photoreactor. Such blank experiment incude experiments under dark conditions, experiments with light but without a photocatalyst and experiments under light in the presence of the photocatalyst but without the targeted reactants."@en ; + skos:inScheme cs: ; + skos:prefLabel "blank experiment"@en . + +cs:0000125 a skos:Concept ; + dcterms:identifier "voc4cat_0000125"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000124 ; + skos:definition "In photocatalytic processes where product formation is expected, selectivity describes the ability of a photocatalyst to produce only the desired product with minimal (or none) of byproducts."@en ; + skos:inScheme cs: ; + skos:prefLabel "selectivity"@en . + +cs:0000126 a skos:Concept ; + dcterms:identifier "voc4cat_0000126"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "AQY"@en, + "AQY%"@en, + "apparent photonic yield"@en ; + skos:broader cs:0000124 ; + skos:definition "A measure of the efficiency of a photocatalytic reaction. It is expressed as the number of consumed charge carriers divided by the number of incident photons."@en ; + skos:inScheme cs: ; + skos:prefLabel "apparent quantum yield"@en . + +cs:0000127 a skos:Concept ; + dcterms:identifier "voc4cat_0000127"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000124 ; + skos:definition "The concentration (usually in ppm or mol) of the products formed during a photocatalytic reaction."@en ; + skos:inScheme cs: ; + skos:prefLabel "product concentration"@en . + +cs:0000132 a skos:Concept ; + dcterms:identifier "voc4cat_0000132"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "FID"@en ; + skos:broader cs:0000131 ; + skos:definition "A type of gas chromatography detector that detects and quantifies the concentration of organic compounds in a gas sample emerging from a column, by measuring the electrical current generated by ionized gas constituents in a hydrogen flame."@en ; + skos:inScheme cs: ; + skos:prefLabel "flame ionization detector"@en . + +cs:0000133 a skos:Concept ; + dcterms:identifier "voc4cat_0000133"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "TCD"@en ; + skos:broader cs:0000131 ; + skos:definition "A type of gas chromatography detector that measures the thermal conductivity of a gas sample and identifies its constituent molecules through changes in a filament’s temperature."@en ; + skos:inScheme cs: ; + skos:prefLabel "thermal conductivity detector"@en . + +cs:0000134 a skos:Concept ; + dcterms:identifier "voc4cat_0000134"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "BID"@en ; + skos:broader cs:0000131 ; + skos:definition "Detector incorporating Ionization via a new dielectric barrier discharge He plasma."@en ; + skos:inScheme cs: ; + skos:prefLabel "dielectric-barrier discharge ionization detector"@en . + +cs:0000135 a skos:Concept ; + dcterms:identifier "voc4cat_0000135"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000130 ; + skos:definition "The minimum concentration of a product or intermediate that the gas chromatograph can identify. "@en ; + skos:inScheme cs: ; + skos:prefLabel "gas chromatograph sensitivity"@en . + +cs:0000136 a skos:Concept ; + dcterms:identifier "voc4cat_0000136"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000130 ; + skos:definition "A process in which gaseous substances of known purity and concentration are introduced to the gas chromatograph and the respective area and retention time of the resulting peaks are identified. This process when concluded, allows for the calculation of concentrations of products and intermediates of the photoreaction."@en ; + skos:inScheme cs: ; + skos:prefLabel "gas chromatograph calibration"@en . + +cs:0000138 a skos:Concept ; + dcterms:identifier "voc4cat_0000138"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000137 ; + skos:definition "Detectors of the mass spectrometer used to identify the reaction products and intemediates."@en ; + skos:inScheme cs: ; + skos:prefLabel "mass spectrometer detector"@en . + +cs:0000139 a skos:Concept ; + dcterms:identifier "voc4cat_0000139"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000137 ; + skos:definition "The minimum concentration of a product or intermediate that the mass spectrometer can identify. "@en ; + skos:inScheme cs: ; + skos:prefLabel "mass spectrometer sensitivity"@en . + +cs:0000140 a skos:Concept ; + dcterms:identifier "voc4cat_0000140"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000137 ; + skos:definition "A process in which gaseous substances of known purity and concentration are introduced to the mass spectrometer and the respective mass-to-charge ratios are identified. This process when concluded, allows for the calculation of concentrations of products and intermediates of the photoreaction."@en ; + skos:inScheme cs: ; + skos:prefLabel "mass spectrometer calibration"@en . + +cs:0000144 a skos:Concept ; + dcterms:identifier "voc4cat_0000144"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000143 ; + skos:definition "Maximum of operation pressure range within the reactor can operate safely. "@en ; + skos:inScheme cs: ; + skos:prefLabel "maximum operation pressure"@en . + +cs:0000145 a skos:Concept ; + dcterms:identifier "voc4cat_0000145"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000143 ; + skos:definition "Minimum of operation pressure range within the reactor can operate safely. "@en ; + skos:inScheme cs: ; + skos:prefLabel "minimum operation pressure"@en . + +cs:0000147 a skos:Concept ; + dcterms:identifier "voc4cat_0000147"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000146 ; + skos:definition "Α mechanical device that removes gas molecules from a sealed chamber reaching pressures lower than the atmospheric pressure. "@en ; + skos:inScheme cs: ; + skos:prefLabel "vacuum pump"@en . + +cs:0000149 a skos:Concept ; + dcterms:identifier "voc4cat_0000149"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000148 ; + skos:definition "Maximum of operation temperature range within the reactor can operate safely."@en ; + skos:inScheme cs: ; + skos:prefLabel "maximum operation temperature"@en . + +cs:0000150 a skos:Concept ; + dcterms:identifier "voc4cat_0000150"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000148 ; + skos:definition "Minimum of operation temperature range within the reactor can operate safely."@en ; + skos:inScheme cs: ; + skos:prefLabel "minimum operation temperature"@en . + +cs:0000151 a skos:Concept ; + dcterms:identifier "voc4cat_0000151"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "temperature controller; temperature gauge; temperature monitor; heating device; cooling device"@en ; + skos:broader cs:0000148 ; + skos:definition "Equipment used for controlling and/or monitoring the temperature in various parts of a photoreactor. This can include hot plates, heating elements and cryostats. Light sources in operation can also affect the temperature in the reaction chamber."@en ; + skos:inScheme cs: ; + skos:prefLabel "temperature controller and monitor"@en . + +cs:0000153 a skos:Concept ; + dcterms:identifier "voc4cat_0000153"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000152 ; + skos:definition "Volume of the reaction chamber, calculated by its dimensions. Volume of pipes and valves connected to the reaction chamber should also be calculated and added to the total volume. "@en ; + skos:inScheme cs: ; + skos:prefLabel "reaction chamber volume"@en . + +cs:0000154 a skos:Concept ; + dcterms:identifier "voc4cat_0000154"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000152 ; + skos:definition "Height, width and depth (in cubic- or rectangular- shaped reaction chambers) or diameter and height (in cylindrer - shaped reaction chambers)"@en ; + skos:inScheme cs: ; + skos:prefLabel "reaction chamber dimension"@en . + +cs:0000155 a skos:Concept ; + dcterms:identifier "voc4cat_0000155"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000152 ; + skos:definition "The shape of the reaction chamber. In gas-phase reactions, reaction chambers have usually a cylindrical, cubical or rectangular shape."@en ; + skos:inScheme cs: ; + skos:prefLabel "reaction chamber shape"@en . + +cs:0000156 a skos:Concept ; + dcterms:identifier "voc4cat_0000156"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000152 ; + skos:definition "Material used for the construction of the main body of the reaction chamber."@en ; + skos:inScheme cs: ; + skos:prefLabel "reaction chamber material"@en . + +cs:0000158 a skos:Concept ; + dcterms:identifier "voc4cat_0000158"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000157 ; + skos:definition "Material that the window is made of. The window, usually attached to the lid sealing the reaction chamber, allows for the incoming light to enter the reaction chamber and interact with the photocatalyst. The material of the window influences the wavelenth range the the photocatalyst experieneces. "@en ; + skos:inScheme cs: ; + skos:prefLabel "optical window material"@en . + +cs:0000160 a skos:Concept ; + dcterms:identifier "voc4cat_0000160"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000159 ; + skos:definition "Diameter of the optical window allowing the incoming light to enter the reaction chamber and interact with the photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "optical window diameter"@en . + +cs:0000161 a skos:Concept ; + dcterms:identifier "voc4cat_0000161"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000159 ; + skos:definition "Thickness of the optical window allowing the incoming light to enter the reaction chamber and interact with the photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "optical window thickness"@en . + +cs:0000164 a skos:Concept ; + dcterms:identifier "voc4cat_0000164"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "MFC"@en, + "MFCs"@en ; + skos:broader cs:0000163 ; + skos:definition "Devices used to control and monitor gas or liquid flow rates."@en ; + skos:inScheme cs: ; + skos:prefLabel "mass flow controller"@en . + +cs:0000167 a skos:Concept ; + dcterms:identifier "voc4cat_0000167"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "Hg-Xe lamp"@en, + "Hg/Xe lamp"@en, + "mercury xenon lamp"@en ; + skos:broader cs:0000166 ; + skos:definition "A lamp containg a mixture of mercury (Hg) and xenon (Xe) gases. Under electric current, the gas mixture gets ionized through a discharge electric charge creating a plasma generating UV and visible light. "@en ; + skos:inScheme cs: ; + skos:prefLabel "mercury-xenon lamp"@en . + +cs:0000168 a skos:Concept ; + dcterms:identifier "voc4cat_0000168"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "Xe lamp"@en, + "Xe-lamp"@en ; + skos:broader cs:0000166 ; + skos:definition "A lamp containg pure xenon (Xe) gas. Under electric current, the gas mixture gets ionized through a discharge electric charge creating a plasma generating UV and visible light. "@en ; + skos:inScheme cs: ; + skos:prefLabel "xenon lamp"@en . + +cs:0000169 a skos:Concept ; + dcterms:identifier "voc4cat_0000169"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "LED"@en, + "light-emitting diode"@en ; + skos:broader cs:0000166 ; + skos:definition "A solid-state semiconductor emitting light at highly controllable (narrow) wavelength ranges."@en ; + skos:inScheme cs: ; + skos:prefLabel "light emitting diode"@en . + +cs:0000171 a skos:Concept ; + dcterms:identifier "voc4cat_0000171"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000170 ; + skos:definition "The distance of the light source from the reaction chamber and the photocatalyst."@en ; + skos:inScheme cs: ; + skos:prefLabel "light source distance"@en . + +cs:0000172 a skos:Concept ; + dcterms:identifier "voc4cat_0000172"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000170 ; + skos:definition "The value of current (usually in A or mA) used to operate the selected light source."@en ; + skos:inScheme cs: ; + skos:prefLabel "light operation current"@en . + +cs:0000173 a skos:Concept ; + dcterms:identifier "voc4cat_0000173"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000170 ; + skos:definition "The value of voltage (usually in V or mV) used to operate the selected light source."@en ; + skos:inScheme cs: ; + skos:prefLabel "light operation voltage"@en . + +cs:0000174 a skos:Concept ; + dcterms:identifier "voc4cat_0000174"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000170 ; + skos:definition "The power of the light source (usually in W or mW). The power can be calculated by the multiplication of the current and voltage used to operate the light source,"@en ; + skos:inScheme cs: ; + skos:prefLabel "light power output"@en . + +cs:0000175 a skos:Concept ; + dcterms:identifier "voc4cat_0000175"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000170 ; + skos:definition "The light intensity (usually in mW cm-2) of the selected light source. The light intensity should be measured at the same distance as the one between the light source and the reaction chamber / sample."@en ; + skos:inScheme cs: ; + skos:prefLabel "light intensity"@en . + +cs:0000177 a skos:Concept ; + dcterms:identifier "voc4cat_0000177"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "IR; Ir"@en ; + skos:broader cs:0000176 ; + skos:definition "Electromagnetic radiation with wavelengths typically in the range of 800 nm - 20000 nm."@en ; + skos:inScheme cs: ; + skos:prefLabel "infrared"@en . + +cs:0000178 a skos:Concept ; + dcterms:identifier "voc4cat_0000178"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "Vis; VIS"@en ; + skos:broader cs:0000176 ; + skos:definition "Electromagnetic radiation with wavelengths visible to the human eye, typically in the range of 400-800 nm. "@en ; + skos:inScheme cs: ; + skos:prefLabel "visible"@en . + +cs:0000179 a skos:Concept ; + dcterms:identifier "voc4cat_0000179"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "UV"@en, + "UV-A"@en, + "UV-B"@en, + "UV-C"@en, + "VUV"@en ; + skos:broader cs:0000176 ; + skos:definition "Electromagnetic radiation with a wavelength typically in the range of 100-400 nanometers."@en ; + skos:inScheme cs: ; + skos:prefLabel "ultraviolet"@en . + +cs:0001900 a skos:Collection ; + dcterms:identifier "voc4cat_0001900"^^xsd:token ; + dcterms:isPartOf cs: ; + dcterms:provenance "Self"@en ; + skos:definition "A collection of concepts referring to material characterization techniques and methods to evaluate their efficiency in photocatalysis."@en ; + skos:member cs:0000067, + cs:0000068, + cs:0000069, + cs:0000070, + cs:0000071, + cs:0000072, + cs:0000073, + cs:0000074, + cs:0000075, + cs:0000076, + cs:0000077, + cs:0000078, + cs:0000079, + cs:0000080, + cs:0000081, + cs:0000082, + cs:0000083, + cs:0000130, + cs:0000137, + cs:0000141 ; + skos:prefLabel "Characterization and evaluation techniques"@en . + +cs:0001901 a skos:Collection ; + dcterms:identifier "voc4cat_0001901"^^xsd:token ; + dcterms:isPartOf cs: ; + dcterms:provenance "Self"@en ; + skos:definition "A collection of concepts referring to photocatalysis."@en ; + skos:member cs:00000001, + cs:00000002, + cs:00000003, + cs:00000004, + cs:00000005, + cs:00000006, + cs:00000007, + cs:00000008, + cs:00000009, + cs:00000010, + cs:00000011, + cs:00000012, + cs:00000013, + cs:00000014, + cs:00000015, + cs:00000016, + cs:00000017, + cs:00000018, + cs:00000019, + cs:00000020, + cs:00000021, + cs:00000022, + cs:00000023, + cs:00000024, + cs:00000025, + cs:00000026, + cs:00000027, + cs:00000028, + cs:00000029, + cs:00000030, + cs:00000031, + cs:00000032, + cs:00000033, + cs:00000034, + cs:00000035, + cs:00000036, + cs:00000037, + cs:00000038, + cs:00000039, + cs:00000040, + cs:00000041, + cs:00000042, + cs:00000043, + cs:00000044, + cs:00000045, + cs:00000046, + cs:00000047, + cs:00000048, + cs:00000049, + cs:00000050, + cs:00000051, + cs:00000052, + cs:00000053, + cs:00000054, + cs:00000055, + cs:00000056, + cs:00000057, + cs:00000058, + cs:00000059, + cs:00000060, + cs:00000061, + cs:00000062, + cs:00000063, + cs:00000064, + cs:00000065, + cs:00000066, + cs:00000067, + cs:00000068, + cs:00000069, + cs:00000070, + cs:00000071, + cs:00000072, + cs:00000073, + cs:00000074, + cs:00000075, + cs:00000076, + cs:00000077, + cs:00000078, + cs:00000079, + cs:00000080, + cs:00000081, + cs:00000082, + cs:00000083, + cs:00000084, + cs:00000085, + cs:00000086, + cs:00000087, + cs:00000088, + cs:00000089, + cs:00000090, + cs:00000091, + cs:00000092, + cs:00000093, + cs:00000094, + cs:00000095, + cs:00000096, + cs:00000097, + cs:00000098, + cs:00000099, + cs:00000100, + cs:00000101, + cs:00000102, + cs:00000103, + cs:00000104, + cs:00000105, + cs:00000106, + cs:00000107, + cs:00000108, + cs:00000109, + cs:00000110, + cs:00000111, + cs:00000112, + cs:00000113, + cs:00000114, + cs:00000115, + cs:00000116, + cs:00000117, + cs:00000118, + cs:00000119, + cs:00000120, + cs:00000121, + cs:00000122, + cs:00000123, + cs:00000124, + cs:00000125, + cs:00000126, + cs:00000127, + cs:00000128, + cs:00000129, + cs:00000130, + cs:00000131, + cs:00000132, + cs:00000133, + cs:00000134, + cs:00000135, + cs:00000136, + cs:00000137, + cs:00000138, + cs:00000139, + cs:00000140, + cs:00000141, + cs:00000142, + cs:00000143, + cs:00000144, + cs:00000145, + cs:00000146, + cs:00000147, + cs:00000148, + cs:00000149, + cs:00000150, + cs:00000151, + cs:00000152, + cs:00000153, + cs:00000154, + cs:00000155, + cs:00000156, + cs:00000157, + cs:00000158, + cs:00000159, + cs:00000160, + cs:00000161, + cs:00000162, + cs:00000163, + cs:00000164, + cs:00000165, + cs:00000166, + cs:00000167, + cs:00000168, + cs:00000169, + cs:00000170, + cs:00000171, + cs:00000172, + cs:00000173, + cs:00000174, + cs:00000175, + cs:00000176, + cs:00000177, + cs:00000178, + cs:00000179 ; + skos:prefLabel "Photocatalysis collection"@en . + +cs:0000004 a skos:Concept ; + dcterms:identifier "voc4cat_0000004"^^xsd:token ; + dcterms:provenance "self"@en ; + skos:broader cs:0000003 ; + skos:definition "Broad families of semiconduction materials (e.g., metal oxides) that can be used as photocatalysts in various applications."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000005 ; + skos:prefLabel "categories of semiconductors"@en . + +cs:0000014 a skos:Concept ; + dcterms:identifier "voc4cat_0000014"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000003 ; + skos:definition "Tecniques used to modify the properties of a photocatalyst, with the aim to increase its efficiency in a photocatalytic application. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000015 ; + skos:prefLabel "modification technique"@en . + +cs:0000017 a skos:Concept ; + dcterms:identifier "voc4cat_0000017"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000016 ; + skos:definition "A photocatalyst introduced to the reaction chamber in the form of a powder. Usually the powdered photocatalyst is spread inside a quartz / glass plate."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000018 ; + skos:prefLabel "powdered photocatalyst"@en . + +cs:0000067 a skos:Concept ; + dcterms:identifier "voc4cat_0000067"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "X-ray emission spectrometry"@en, + "X-ray fluorescence spectrometry; X-ray fluorescence spectroscopy"@en, + "XES"@en, + "XRES"@en, + "XRF"@en, + "XRF spectrometry"@en, + "XRF spectroscopy"@en ; + skos:broader cs:0000066 ; + skos:definition "A non-destructive analytical technique which uses a high-energy X-ray source to expose a material and monitors the emitted characteristic fluorescent X-Rays. "@en ; + skos:inScheme cs: ; + skos:prefLabel "X-ray fluorescence"@en . + +cs:0000068 a skos:Concept ; + dcterms:identifier "voc4cat_0000068"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "EELS"@en ; + skos:broader cs:0000066 ; + skos:definition "An analytical technique used to measure the energy loss of electrons passing through a sample. "@en ; + skos:inScheme cs: ; + skos:prefLabel "electron energy loss spectroscopy"@en . + +cs:0000069 a skos:Concept ; + dcterms:identifier "voc4cat_0000069"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "RAMAN"@en, + "Raman"@en, + "Raman scattering spectrometry"@en, + "Raman spectrometry"@en, + "raman scattering spectroscopy"@en ; + skos:broader cs:0000066 ; + skos:definition "A spectroscopy technique studying the vibrational modes of molecules, by measuring the intensity and frequency of scattered by the sample of monochromatic light. "@en ; + skos:inScheme cs: ; + skos:prefLabel "Raman spectroscopy"@en . + +cs:0000070 a skos:Concept ; + dcterms:identifier "voc4cat_0000070"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "AFM"@en, + "SFM"@en, + "atomic force imaging"@en, + "atomic-force microscopy"@en, + "scanning force microscopy"@en ; + skos:broader cs:0000066 ; + skos:definition "A high-resolution imaging technique that measures the interaction between a sharp probe and the sample’s surface to create a three-dimensional image of the surface’s morphology. "@en ; + skos:inScheme cs: ; + skos:prefLabel "atomic force microscopy"@en . + +cs:0000071 a skos:Concept ; + dcterms:identifier "voc4cat_0000071"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "DSC"@en, + "differential scanning calorimetric (DSC) analysis"@en, + "differential scanning calorimetric analysis"@en ; + skos:broader cs:0000066 ; + skos:definition "A thermal analysis technique which compares the heat flow in a sample and a reference material under controlled applied temperature profiles. "@en ; + skos:inScheme cs: ; + skos:prefLabel "differential scanning calorimetry"@en . + +cs:0000072 a skos:Concept ; + dcterms:identifier "voc4cat_0000072"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "TG"@en, + "TG analysis"@en, + "TG measurements"@en, + "TGA"@en, + "thermal gravimetric analysis"@en, + "thermo-gravimetric analysis"@en, + "thermogravimetric (TG) analyses"@en, + "thermogravimetric (TG) analysis"@en ; + skos:broader cs:0000066 ; + skos:definition "A thermal analysis technique used to measure the change of a sample’s mass under the influence of controlled applied temperature profiles."@en ; + skos:inScheme cs: ; + skos:prefLabel "thermogravimetric analysis"@en . + +cs:0000073 a skos:Concept ; + dcterms:identifier "voc4cat_0000073"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "NMR"@en ; + skos:broader cs:0000066 ; + skos:definition "A spectroscopic technique that uses a static magnetic field and radiofrequency radiation to measure the magnetic resonance of atomic nuclei protons or electrons."@en ; + skos:inScheme cs: ; + skos:prefLabel "nuclear magnetic resonance spectroscopy"@en . + +cs:0000074 a skos:Concept ; + dcterms:identifier "voc4cat_0000074"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "PL"@en ; + skos:broader cs:0000066 ; + skos:definition "Light emission of lower energy photons from a sample upon its photoexcitation. "@en ; + skos:inScheme cs: ; + skos:prefLabel "photoluminescence"@en . + +cs:0000075 a skos:Concept ; + dcterms:identifier "voc4cat_0000075"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "SEM"@en ; + skos:broader cs:0000066 ; + skos:definition "An electron microscopy technique that produces high-resolution images under high magnification of a sample's surface by assessing the secondary and back-scattered electrons produced by a focused electron beam."@en ; + skos:inScheme cs: ; + skos:prefLabel "scanning electron microscopy"@en . + +cs:0000076 a skos:Concept ; + dcterms:identifier "voc4cat_0000076"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "XPS"@en ; + skos:broader cs:0000066 ; + skos:definition "A technique that analyzes the chemical composition of an X-ray irradiated sample by measuring the energies of the emitted electrons."@en ; + skos:inScheme cs: ; + skos:prefLabel "X-ray photoelectron spectroscopy"@en . + +cs:0000077 a skos:Concept ; + dcterms:identifier "voc4cat_0000077"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "X-ray analysis"@en, + "X-ray crystallographic analysis"@en, + "X-ray crystallography"@en, + "X-ray diffraction analysis"@en, + "X-ray diffractometry"@en, + "X-ray structure determination"@en, + "XRD"@en ; + skos:broader cs:0000066 ; + skos:definition "A technique which analyses the diffraction pattern produced when X-rays are scattered by a sample bombarded by a focused electron beam."@en ; + skos:inScheme cs: ; + skos:prefLabel "X-ray diffraction"@en . + +cs:0000078 a skos:Concept ; + dcterms:identifier "voc4cat_0000078"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "TEM"@en ; + skos:broader cs:0000066 ; + skos:definition "Transmission electron microscopy is a technique that produces high-resolution images if the internal structure of a sample by using a beam of electrons to bombard the thin sample and measuring the intensity of the scattered transmitted electrons."@en ; + skos:inScheme cs: ; + skos:prefLabel "transmission electron microscopy"@en . + +cs:0000079 a skos:Concept ; + dcterms:identifier "voc4cat_0000079"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "UV-Vis"@en ; + skos:broader cs:0000066 ; + skos:definition "A technique used to measure the absorption, transmission or reflectance of light by a sample in the ultraviolet and visible regions of the electromagnetic spectrum."@en ; + skos:inScheme cs: ; + skos:prefLabel "ultraviolet-visible spectroscopy"@en . + +cs:0000080 a skos:Concept ; + dcterms:identifier "voc4cat_0000080"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "FT-IR"@en, + "FT-IR spectroscopy"@en, + "FTIR"@en, + "FTIR spectrometry"@en, + "FTIR spectroscopy"@en, + "Fourier transform infra-red absoprtion spectroscopy"@en, + "Fourier transform infra-red spectrometry"@en, + "Fourier transform infrared (FT-IR)"@en, + "Fourier transform infrared (FT-IR) spectroscopy"@en, + "Fourier-transform infra-red absorption spectrometry"@en, + "Fourier-transform infrared (FTIR) absorption spectroscopy"@en ; + skos:broader cs:0000066 ; + skos:definition "A spectroscopic technique used to study the vibrational modes of chemical bonds of a sample using infrared radiation."@en ; + skos:inScheme cs: ; + skos:prefLabel "fourier transform infrared spectroscopy"@en . + +cs:0000081 a skos:Concept ; + dcterms:identifier "voc4cat_0000081"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "BET"@en ; + skos:broader cs:0000066 ; + skos:definition "The study of physical adsorption of gas molecules on a solid surface for the calculation of the specific surface area of materials."@en ; + skos:inScheme cs: ; + skos:prefLabel "Brunauer-Emmett-Teller surface area analysis"@en . + +cs:0000082 a skos:Concept ; + dcterms:identifier "voc4cat_0000082"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "CV"@en, + "cyclovoltammetry"@en ; + skos:broader cs:0000066 ; + skos:definition "An electrochemical technique used to study the redox properties of a sample by measuring the current produced by an applied voltage sweep."@en ; + skos:inScheme cs: ; + skos:prefLabel "cyclic voltammetry"@en . + +cs:0000083 a skos:Concept ; + dcterms:identifier "voc4cat_0000083"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000066 ; + skos:definition "A method used in cyclic voltammetry to determine the charge carrier concentration and the flat-band potential of an electrochemical system by measuring the capacitance as a function of applied voltage."@en ; + skos:inScheme cs: ; + skos:prefLabel "Mott-Schottky analysis"@en . + +cs:0000098 a skos:Concept ; + dcterms:identifier "voc4cat_0000098"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000087 ; + skos:definition "The gain of electrons or a decrease in the oxidation state of a species. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000099 ; + skos:prefLabel "reduction"@en . + +cs:0000141 a skos:Concept ; + dcterms:identifier "voc4cat_0000141"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "LC"@en ; + skos:broader cs:0000129 ; + skos:definition "A sepation technique that uses a liquid mobile phase to separate the components of a mixture based on their interactions with a stationary phase and a mobile phase. "@en ; + skos:inScheme cs: ; + skos:prefLabel "liquid chromatography"@en . + +cs:0000146 a skos:Concept ; + dcterms:identifier "voc4cat_0000146"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "pressure controller; pressure gauge; pressure monitor"@en ; + skos:broader cs:0000143 ; + skos:definition "Equipment used for controlling and / or monitoring the pressure in various parts of a photoreactor. A vaccum pump is a typical example of such equipment."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000147 ; + skos:prefLabel "pressure controller and monitor"@en . + +cs:0000162 a skos:Concept ; + dcterms:identifier "voc4cat_0000162"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "gas flow"@en ; + skos:broader cs:0000128 ; + skos:definition "Flow rates of gases used in an experiment. Gases can have either the role of a reactant (e.g., CO2) or be inert (e.g., Ar, He). "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000163 ; + skos:prefLabel "gas feed"@en . + +cs:0000163 a skos:Concept ; + dcterms:identifier "voc4cat_0000163"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000162 ; + skos:definition "Equipment used for controlling and / or monitoring the flow of gases (reactant or inert) needed for a photocatalytic experiment. Mass flow controllers (MFCs) are commonly used to controll gas flows."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000164 ; + skos:prefLabel "gas flow controller and monitor"@en . + +cs:0000016 a skos:Concept ; + dcterms:identifier "voc4cat_0000016"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000002 ; + skos:definition "The form in which the photocatalyst is introduced to the reaction chamber. This can include e.g., powders, pellets or thin films deposited on a substrate. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000017, + cs:0000019 ; + skos:prefLabel "sample form"@en . + +cs:0000024 a skos:Concept ; + dcterms:identifier "voc4cat_0000024"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000019 ; + skos:definition "The substate onto which a (powdered) photocatalyst is deposited. Such substrates incude glass surfaces (e.g., borosilicate glass or conductive glass like ITO and FTO), ceramic substrates (e.g., alumina) or metal substrates (e.g., Ti foils, stainless steel etc.) "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000025, + cs:0000033 ; + skos:prefLabel "substrate"@en . + +cs:0000038 a skos:Concept ; + dcterms:identifier "voc4cat_0000038"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000019 ; + skos:definition "A thin film of the photocatalyst deposited on an appropiate for the application substrate."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000039, + cs:0000040 ; + skos:prefLabel "deposited sample"@en . + +cs:0000045 a skos:Concept ; + dcterms:identifier "voc4cat_0000045"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000002 ; + skos:definition "The process by which one or more chemical reactions are performed with the aim of converting a reactant or starting material into a product or multiple products."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000046, + cs:0000049 ; + skos:prefLabel "synthesis"@en . + +cs:0000046 a skos:Concept ; + dcterms:identifier "voc4cat_0000046"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "publications; papers; manuscripts;"@en ; + skos:broader cs:0000045 ; + skos:definition "Thorough search of available literature on the research topic of interest using online research platforms (e.g, Scopus, Google Scholar, Web of Science, Research Gate etc.) and / or libraries. Relevant literature can be found in the form of publications, books, abstracts and conference presentations. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000047, + cs:0000048 ; + skos:prefLabel "literature research"@en . + +cs:0000084 a skos:Concept ; + dcterms:identifier "voc4cat_0000084"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000001 ; + skos:definition "The energy state occupied by an electron in a photocatalyst. This state cab affect the electron's ability to participate in a photocatalytic reaction. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000085, + cs:0000086 ; + skos:prefLabel "electronic state"@en . + +cs:0000105 a skos:Concept ; + dcterms:identifier "voc4cat_0000105"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000101 ; + skos:definition "Electron donors or hole scavengers used to reduce the recombination tendency of electrons and holes. Sacrificial reagents are used in photocatalysis to study an oxidation or reduction reaction seperately."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000106, + cs:0000107 ; + skos:prefLabel "sacrificial reagant"@en . + +cs:0000108 a skos:Concept ; + dcterms:identifier "voc4cat_0000108"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "Operation mode under the which the experiment takes place: batch of continuous flow mode."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000109, + cs:0000110 ; + skos:prefLabel "operation mode"@en . + +cs:0000115 a skos:Concept ; + dcterms:identifier "voc4cat_0000115"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "The temperature (range) under which the photocatalytic reaction takes place."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000116, + cs:0000117 ; + skos:prefLabel "experiment temperature"@en . + +cs:0000118 a skos:Concept ; + dcterms:identifier "voc4cat_0000118"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "The pressure (range) under which the photocatalytic reaction takes place."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000119, + cs:0000120 ; + skos:prefLabel "experiment pressure"@en . + +cs:0000142 a skos:Concept ; + dcterms:identifier "voc4cat_0000142"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000128 ; + skos:definition "The range of critical for the safe operation of the photoreactor parameters."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000143, + cs:0000148 ; + skos:prefLabel "operation parameters"@en . + +cs:0000157 a skos:Concept ; + dcterms:identifier "voc4cat_0000157"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000152 ; + skos:definition "A transparent material optimized to allow the transmission of electromagnetic radiation with low reflectance and scattering. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000158, + cs:0000159 ; + skos:prefLabel "optical window"@en . + +cs:0000159 a skos:Concept ; + dcterms:identifier "voc4cat_0000159"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000157 ; + skos:definition "The dimension of the optical window (diameter / thickness) allowing the incoming light to enter the reaction chamber and interact with the photocatalyst."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000160, + cs:0000161 ; + skos:prefLabel "optical window dimensions"@en . + +cs:0000165 a skos:Concept ; + dcterms:identifier "voc4cat_0000165"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000128 ; + skos:definition "The irradiation system includes all the necessary equipment needed to perform a photocatalytic experiment. The system apart from the light source can include, filters, power units, lamp cooling devices etc."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000166, + cs:0000170 ; + skos:prefLabel "irradiation system"@en . + +cs:0000003 a skos:Concept ; + dcterms:identifier "voc4cat_0000003"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000002 ; + skos:definition "A material with electrical conductivity between that of a conductor and an insulator."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000004, + cs:0000006, + cs:0000014 ; + skos:prefLabel "semiconductor"@en . + +cs:0000019 a skos:Concept ; + dcterms:identifier "voc4cat_0000019"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000016 ; + skos:definition "A photocatalyst introduced to the reaction chamber in the form of a thin film. To form a thin film, a (powdered) photocatalyst is deposited on a substrate (e.g., glass or metal) using an appropriate deposition technique. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000020, + cs:0000024, + cs:0000038 ; + skos:prefLabel "thin film"@en . + +cs:0000020 a skos:Concept ; + dcterms:identifier "voc4cat_0000020"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000019 ; + skos:definition "A technique used to deposit (immobilize) a (powdered) photocatalyst on a substate. These techniques indlude (but are not limited to): doctor blading, spin coating, spray coating, etc."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000021, + cs:0000022, + cs:0000023 ; + skos:prefLabel "deposition technique"@en . + +cs:0000025 a skos:Concept ; + dcterms:identifier "voc4cat_0000025"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000024 ; + skos:definition "The material that the substrate is made of. Common materials include: glass (conductive or not), ceramics and metal."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000026, + cs:0000027, + cs:0000032 ; + skos:prefLabel "substrate material"@en . + +cs:0000062 a skos:Concept ; + dcterms:identifier "voc4cat_0000062"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000049 ; + skos:definition "Chemical substances used in the synthesis process of a desired photocatalyst."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000063, + cs:0000064, + cs:0000065 ; + skos:prefLabel "chemical substance for synthesis"@en . + +cs:0000111 a skos:Concept ; + dcterms:identifier "voc4cat_0000111"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "The total duration of an experiment"@en ; + skos:inScheme cs: ; + skos:narrower cs:0000112, + cs:0000113, + cs:0000114 ; + skos:prefLabel "experiment duration"@en . + +cs:0000124 a skos:Concept ; + dcterms:identifier "voc4cat_0000124"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "Quantitative and qualitative evaluation of the outcome of a photocatalytic reaction (e.g., product formation from the photoreduction of CO2). The evaluation can lead to changes in the synthesis of the photocatalyst and / or selecting different experimental parameters."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000125, + cs:0000126, + cs:0000127 ; + skos:prefLabel "evaluation"@en . + +cs:0000129 a skos:Concept ; + dcterms:identifier "voc4cat_0000129"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000128 ; + skos:definition "Spectroscopic or chromatographic methods used to qualitatively and quantitatively identify the products of the photoreaction. Such devices are usually attached to the photoreactor, or a sample is being trasfered to an identification method via another medium (e.g., gastight syringes)."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000130, + cs:0000137, + cs:0000141 ; + skos:prefLabel "product identification method"@en . + +cs:0000131 a skos:Concept ; + dcterms:identifier "voc4cat_0000131"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000130 ; + skos:definition "Detectors of the gas chromatogragh used to identify the reaction products and intemediates."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000132, + cs:0000133, + cs:0000134 ; + skos:prefLabel "gas chromatograph detector"@en . + +cs:0000143 a skos:Concept ; + dcterms:identifier "voc4cat_0000143"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "range of operation pressure; operation pressure range; \\Ppressure range"@en ; + skos:broader cs:0000142 ; + skos:definition "Maximum and minimum of operation pressure range within the reactor can operate safely. Higher operation temperatures can lead to higher pressure values."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000144, + cs:0000145, + cs:0000146 ; + skos:prefLabel "operation pressure"@en . + +cs:0000148 a skos:Concept ; + dcterms:identifier "voc4cat_0000148"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "range of operation temperature; operation temperature range; temparature range"@en ; + skos:broader cs:0000142 ; + skos:definition "Maximum and minimum of operation temperature range within the reactor can operate safely."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000149, + cs:0000150, + cs:0000151 ; + skos:prefLabel "operation temperature"@en . + +cs:0000166 a skos:Concept ; + dcterms:identifier "voc4cat_0000166"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000165 ; + skos:definition "Light source used to irradiate a photocatalyst in a reaction chamber. These include sources with various intensities, powers and wavelength ranges, including Hg/Xe lamps, Xe lamps and LEDs. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000167, + cs:0000168, + cs:0000169 ; + skos:prefLabel "light source"@en . + +cs:0000176 a skos:Concept ; + dcterms:identifier "voc4cat_0000176"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "λ"@en ; + skos:broader cs:0000170 ; + skos:definition "The distance between two successive peaks or troughs in a wave."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000177, + cs:0000178, + cs:0000179 ; + skos:prefLabel "light wavelength"@en . + +cs:0000002 a skos:Concept ; + dcterms:identifier "voc4cat_0000002"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "photocatalytic material"@en ; + skos:broader cs:0000001 ; + skos:definition "A material that absorbs photons (light) of appropriate energy and initiates or accelerates a photochemical reaction, while it regenerates itself after each reaction cycle. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000003, + cs:0000016, + cs:0000045, + cs:0000066 ; + skos:prefLabel "photocatalyst"@en . + +cs:0000027 a skos:Concept ; + dcterms:identifier "voc4cat_0000027"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000025 ; + skos:definition "A flat surface made of glass serving as a substrate for the deposition of a photocatalyst."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000028, + cs:0000029, + cs:0000030, + cs:0000031 ; + skos:prefLabel "glass substrate"@en . + +cs:0000033 a skos:Concept ; + dcterms:identifier "voc4cat_0000033"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000024 ; + skos:definition "The diamensions of the substrate."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000034, + cs:0000035, + cs:0000036, + cs:0000037 ; + skos:prefLabel "substrate dimension"@en . + +cs:0000040 a skos:Concept ; + dcterms:identifier "voc4cat_0000040"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000038 ; + skos:definition "The diamensions of the - deposited on the substrate - thin film"@en ; + skos:inScheme cs: ; + skos:narrower cs:0000041, + cs:0000042, + cs:0000043, + cs:0000044 ; + skos:prefLabel "thin film dimension"@en . + +cs:0000101 a skos:Concept ; + dcterms:identifier "voc4cat_0000101"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000100 ; + skos:definition "The starting substances that undergo a chemical reaction to produce a desired product."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000102, + cs:0000103, + cs:0000104, + cs:0000105 ; + skos:prefLabel "reactant"@en . + +cs:0000130 a skos:Concept ; + dcterms:identifier "voc4cat_0000130"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "GC"@en ; + skos:broader cs:0000129 ; + skos:definition "An analytical technique that separates and analyzes the components of a gas mixture by passing it though a stationary phase."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000131, + cs:0000135, + cs:0000136 ; + skos:prefLabel "gas chromatography"@en . + +cs:0000137 a skos:Concept ; + dcterms:identifier "voc4cat_0000137"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "MS"@en ; + skos:broader cs:0000129 ; + skos:definition "An analytical technique which determines the mass-to-charge ratio of ions in a sample to give information about the composition of the sample."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000138, + cs:0000139, + cs:0000140 ; + skos:prefLabel "mass spectrometry"@en . + +cs:0000001 a skos:Concept ; + dcterms:identifier "voc4cat_0000001"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "photocatalytic reaction"@en ; + skos:definition "A process which catalyzes a chemical reaction through the absorption of sufficient light energy by a photocatalyst. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000002, + cs:0000084, + cs:0000087, + cs:0000100, + cs:0000128 ; + skos:prefLabel "photocatalysis"@en ; + skos:topConceptOf cs: . + +cs:0000128 a skos:Concept ; + dcterms:identifier "voc4cat_0000128"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "reactor design; reactor engineering; photoreactor engineering"@en ; + skos:broader cs:0000001 ; + skos:definition "Details describing the construction, physical dimensions, and operation of the photoreactor used to perform a photocatalytic reaction."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000129, + cs:0000142, + cs:0000152, + cs:0000162, + cs:0000165 ; + skos:prefLabel "photoreactor design"@en . + +cs:0000152 a skos:Concept ; + dcterms:identifier "voc4cat_0000152"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:altLabel "photoreaction chamber"@en ; + skos:broader cs:0000128 ; + skos:definition "A construction inside of which the photocatalyst and the reactants coexist and the photoreaction takes place."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000153, + cs:0000154, + cs:0000155, + cs:0000156, + cs:0000157 ; + skos:prefLabel "reaction chamber"@en . + +cs:0000054 a skos:Concept ; + dcterms:identifier "voc4cat_0000054"^^xsd:token ; + dcterms:provenance "self"@en ; + skos:altLabel "heat treatment; heat-treatment; calcination"@en ; + skos:broader cs:0000049 ; + skos:definition "Heat treatment to reach the desired final photocatalyst. The parameters of the heat treatment can vary between each calcination step. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000055, + cs:0000056, + cs:0000057, + cs:0000058, + cs:0000059, + cs:0000060 ; + skos:prefLabel "calcination step"@en . + +cs:0000170 a skos:Concept ; + dcterms:identifier "voc4cat_0000170"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000165 ; + skos:definition "Specific of roperties of the light source dictaning its operation and its adequacy in the studied photocatalytic reaction. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000171, + cs:0000172, + cs:0000173, + cs:0000174, + cs:0000175, + cs:0000176 ; + skos:prefLabel "light source property"@en . + +cs:0000006 a skos:Concept ; + dcterms:identifier "voc4cat_0000006"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000003 ; + skos:definition "Characteristic properties of a semiconductor used in the field of photocatalysis. These properties determine its performance in the studied photocatalytic application."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000007, + cs:0000008, + cs:0000009, + cs:0000010, + cs:0000011, + cs:0000012, + cs:0000013 ; + skos:prefLabel "semiconductor property"@en . + +cs:0000049 a skos:Concept ; + dcterms:identifier "voc4cat_0000049"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000045 ; + skos:definition "Necessary steps needed to follow in order to reach the desired photocatalyst."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000050, + cs:0000051, + cs:0000052, + cs:0000053, + cs:0000054, + cs:0000061, + cs:0000062 ; + skos:prefLabel "synthesis procedure"@en . + +cs:0000100 a skos:Concept ; + dcterms:identifier "voc4cat_0000100"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000001 ; + skos:definition "A lab-scale experiment performed to test the efficiency of a studied photocatalyst in a photocatalytic application (e.g., dye degradation, CO2 photoreduction e.t.c.)."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000101, + cs:0000108, + cs:0000111, + cs:0000115, + cs:0000118, + cs:0000121, + cs:0000122, + cs:0000123, + cs:0000124 ; + skos:prefLabel "photocatalytic experiment"@en . + +cs:0000087 a skos:Concept ; + dcterms:identifier "voc4cat_0000087"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000001 ; + skos:definition "A multi-step process iniatiated by the absorption of photons by a photocatalyst. This process involves various sub-processes that include the photogeneration and transfer of electron and hole pairs. "@en ; + skos:inScheme cs: ; + skos:narrower cs:0000088, + cs:0000089, + cs:0000090, + cs:0000091, + cs:0000092, + cs:0000093, + cs:0000094, + cs:0000095, + cs:0000096, + cs:0000097, + cs:0000098 ; + skos:prefLabel "photocatalytic process"@en . + +cs:0000066 a skos:Concept ; + dcterms:identifier "voc4cat_0000066"^^xsd:token ; + dcterms:provenance "Self"@en ; + skos:broader cs:0000002 ; + skos:definition "A collection of techniques used to identify the (physico)chemical, morphological, structural, mechanical, optical and electrical properties of the syntesized photocatalysts. Characterization is performed after the synthesis of the photocatalysts to evaluate the success of the synthetic approach, but also after the completion of the evaluation of the materials in CO2 photoreduction to ensure their stability under the selected experimental parameters."@en ; + skos:inScheme cs: ; + skos:narrower cs:0000067, + cs:0000068, + cs:0000069, + cs:0000070, + cs:0000071, + cs:0000072, + cs:0000073, + cs:0000074, + cs:0000075, + cs:0000076, + cs:0000077, + cs:0000078, + cs:0000079, + cs:0000080, + cs:0000081, + cs:0000082, + cs:0000083 ; + skos:prefLabel "characterization"@en . + +cs: a skos:ConceptScheme ; + dcterms:created "2023-06-29"^^xsd:date ; + dcterms:creator ; + dcterms:hasPart cs:0001900, + cs:0001901 ; + dcterms:identifier "voc4cat_"^^xsd:token ; + dcterms:modified "2023-06-29"^^xsd:date ; + dcterms:provenance "David Linke (orcid:0000-0002-5898-1820), Nikolaos G. Moustakas (orcid:0000-0002-6242-2167)"@en ; + dcterms:publisher ; + owl:versionInfo "v2023-06-29" ; + skos:definition "A vocabulary for all areas of catalysis initiated in NFDI4Cat. Starting with photocatalysis we add more and more terms from other areas of catalysis and related disciplines like chemical enineering or material science."@en ; + skos:hasTopConcept cs:0000001 ; + skos:prefLabel "Voc4Cat - A SKOS vocabulary for Catalysis."@en ; + dcat:contactPoint "David Linke (orcid:0000-0002-5898-1820), Nikolaos G. 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zDb@#5SWRiZ=Fe~*XkjZenkkHSd|*>jiW18+^U{m;p$x31)GePc*$1@yEf6asyM@si z7_dOkz)gXa6v$?QOA7SB-TX@|N(bmHkOxr>6at1d&_E>5L5xIr5vzd;h57rP6d4#E zyg~D4W4#c%fncMIu!VX5r$?=4f&L2sh8C)`z8j;Pg5)f)Sy-K=-}lvN5ikP(u10qj zt0}sHU}qU)bJn>`$tpcJ28Nn_jA%*Wt_xOEOt6`<`a^%`bD-y*0mB_7K`}aZgH1`! z&&>rEZpHdg2G*qTspDC^3@}T~0VYBPl%x>X12zSo6kx`=KvI~YUKwU4TbAX%svhW` z4Zr{gWn36&VB7&rZ=hU~m;~%oLMW{6N%nC|{tVQ1ALu63D9fCH9yUl(1`Z*tQFgJ{ zJF88Mf#Ldlv|wtSI}zPLaFm&13+yQoMT|y3kIe--3)N$hD=<8UH7yFrOu7RMQHFOw zjOwwyE79G7ouzJkum(A{5z!J#~*kebD|HiIW=mvs4W`@mUyGncYY=IuzgyFGS zz;YHX#;~U58{9m?*geL%8QmR79s|1utH=H`r$12v79_8M0gdXhYZwNCJ!X#0V{6|h zZ~X%d>$5=5p~jfOP7IG>&0xuCt^(LS7PkwJ$H1<^>anMtthTG9J62(7kpz + + + Voc4Cat - A SKOS vocabulary for Catalysis. + + + + + + + + + +
made by + pyLODE + 2.13.2 +
+

Voc4Cat - A SKOS vocabulary for Catalysis.

+

A taxonomy

+
+

Concept Scheme

+
+
URI
+
https://w3id.org/nfdi4cat/voc4cat_
+
Publisher(s)
+
+ +
+
+
Creator(s)
+
+ +
+
+
Created
+
2023-06-29
+
Modified
+
2023-06-29
+
Version Information
+
v2023-06-29
+
Ontology RDF
+
RDF (turtle)
+
+

Description

+
+

A vocabulary for all areas of catalysis initiated in NFDI4Cat. Starting with photocatalysis we add more and more terms from other areas of catalysis and related disciplines like chemical enineering or material science.

+
+
+
+

Table of Contents

+
    +
  1. Collections
    2. +
  2. Concepts
    3. +
  3. Namespaces
    4. +
  4. Legend
    5. +
+
+ +
+

Collections ↑

+ +
+

Characterization and evaluation techniquescol

+ + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0001900
Definition

A collection of concepts referring to material characterization techniques and methods to evaluate their efficiency in photocatalysis.

Members + gas chromatographycon, + cyclic voltammetrycon, + transmission electron microscopycon, + thermogravimetric analysiscon, + X-ray diffractioncon, + Raman spectroscopycon, + liquid chromatographycon, + fourier transform infrared spectroscopycon, + mass spectrometrycon, + scanning electron microscopycon, + ultraviolet-visible spectroscopycon, + X-ray fluorescencecon, + Mott-Schottky analysiscon, + photoluminescencecon, + electron energy loss spectroscopycon, + nuclear magnetic resonance spectroscopycon, + X-ray photoelectron spectroscopycon, + atomic force microscopycon, + Brunauer-Emmett-Teller surface area analysiscon, + differential scanning calorimetrycon +
+
+
+

Photocatalysis collectioncol

+ + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0001901
Definition

A collection of concepts referring to photocatalysis.

Members + https://w3id.org/nfdi4cat/voc4cat_00000004con, + https://w3id.org/nfdi4cat/voc4cat_00000048con, + https://w3id.org/nfdi4cat/voc4cat_00000059con, + https://w3id.org/nfdi4cat/voc4cat_00000099con, + https://w3id.org/nfdi4cat/voc4cat_00000030con, + https://w3id.org/nfdi4cat/voc4cat_00000074con, + https://w3id.org/nfdi4cat/voc4cat_00000080con, + https://w3id.org/nfdi4cat/voc4cat_00000052con, + https://w3id.org/nfdi4cat/voc4cat_00000125con, + https://w3id.org/nfdi4cat/voc4cat_00000062con, + https://w3id.org/nfdi4cat/voc4cat_00000138con, + https://w3id.org/nfdi4cat/voc4cat_00000152con, + https://w3id.org/nfdi4cat/voc4cat_00000053con, + https://w3id.org/nfdi4cat/voc4cat_00000107con, + https://w3id.org/nfdi4cat/voc4cat_00000015con, + https://w3id.org/nfdi4cat/voc4cat_00000177con, + https://w3id.org/nfdi4cat/voc4cat_00000156con, + https://w3id.org/nfdi4cat/voc4cat_00000111con, + https://w3id.org/nfdi4cat/voc4cat_00000105con, + https://w3id.org/nfdi4cat/voc4cat_00000076con, + https://w3id.org/nfdi4cat/voc4cat_00000045con, + https://w3id.org/nfdi4cat/voc4cat_00000007con, + https://w3id.org/nfdi4cat/voc4cat_00000120con, + https://w3id.org/nfdi4cat/voc4cat_00000130con, + https://w3id.org/nfdi4cat/voc4cat_00000012con, + https://w3id.org/nfdi4cat/voc4cat_00000171con, + https://w3id.org/nfdi4cat/voc4cat_00000001con, + https://w3id.org/nfdi4cat/voc4cat_00000032con, + https://w3id.org/nfdi4cat/voc4cat_00000070con, + https://w3id.org/nfdi4cat/voc4cat_00000077con, + https://w3id.org/nfdi4cat/voc4cat_00000162con, + https://w3id.org/nfdi4cat/voc4cat_00000174con, + https://w3id.org/nfdi4cat/voc4cat_00000134con, + https://w3id.org/nfdi4cat/voc4cat_00000110con, + https://w3id.org/nfdi4cat/voc4cat_00000139con, + https://w3id.org/nfdi4cat/voc4cat_00000056con, + https://w3id.org/nfdi4cat/voc4cat_00000058con, + https://w3id.org/nfdi4cat/voc4cat_00000060con, + https://w3id.org/nfdi4cat/voc4cat_00000179con, + https://w3id.org/nfdi4cat/voc4cat_00000067con, + https://w3id.org/nfdi4cat/voc4cat_00000117con, + https://w3id.org/nfdi4cat/voc4cat_00000149con, + https://w3id.org/nfdi4cat/voc4cat_00000034con, + https://w3id.org/nfdi4cat/voc4cat_00000095con, + https://w3id.org/nfdi4cat/voc4cat_00000041con, + https://w3id.org/nfdi4cat/voc4cat_00000163con, + https://w3id.org/nfdi4cat/voc4cat_00000166con, + https://w3id.org/nfdi4cat/voc4cat_00000094con, + https://w3id.org/nfdi4cat/voc4cat_00000137con, + https://w3id.org/nfdi4cat/voc4cat_00000092con, + https://w3id.org/nfdi4cat/voc4cat_00000140con, + https://w3id.org/nfdi4cat/voc4cat_00000158con, + https://w3id.org/nfdi4cat/voc4cat_00000147con, + https://w3id.org/nfdi4cat/voc4cat_00000063con, + https://w3id.org/nfdi4cat/voc4cat_00000129con, + https://w3id.org/nfdi4cat/voc4cat_00000146con, + https://w3id.org/nfdi4cat/voc4cat_00000126con, + https://w3id.org/nfdi4cat/voc4cat_00000124con, + https://w3id.org/nfdi4cat/voc4cat_00000002con, + https://w3id.org/nfdi4cat/voc4cat_00000101con, + https://w3id.org/nfdi4cat/voc4cat_00000025con, + https://w3id.org/nfdi4cat/voc4cat_00000021con, + https://w3id.org/nfdi4cat/voc4cat_00000141con, + https://w3id.org/nfdi4cat/voc4cat_00000085con, + https://w3id.org/nfdi4cat/voc4cat_00000155con, + https://w3id.org/nfdi4cat/voc4cat_00000086con, + https://w3id.org/nfdi4cat/voc4cat_00000118con, + https://w3id.org/nfdi4cat/voc4cat_00000106con, + https://w3id.org/nfdi4cat/voc4cat_00000038con, + https://w3id.org/nfdi4cat/voc4cat_00000122con, + https://w3id.org/nfdi4cat/voc4cat_00000071con, + https://w3id.org/nfdi4cat/voc4cat_00000167con, + https://w3id.org/nfdi4cat/voc4cat_00000165con, + https://w3id.org/nfdi4cat/voc4cat_00000026con, + https://w3id.org/nfdi4cat/voc4cat_00000093con, + https://w3id.org/nfdi4cat/voc4cat_00000084con, + https://w3id.org/nfdi4cat/voc4cat_00000082con, + https://w3id.org/nfdi4cat/voc4cat_00000039con, + https://w3id.org/nfdi4cat/voc4cat_00000017con, + https://w3id.org/nfdi4cat/voc4cat_00000047con, + https://w3id.org/nfdi4cat/voc4cat_00000145con, + https://w3id.org/nfdi4cat/voc4cat_00000108con, + https://w3id.org/nfdi4cat/voc4cat_00000019con, + https://w3id.org/nfdi4cat/voc4cat_00000096con, + https://w3id.org/nfdi4cat/voc4cat_00000013con, + https://w3id.org/nfdi4cat/voc4cat_00000054con, + https://w3id.org/nfdi4cat/voc4cat_00000014con, + https://w3id.org/nfdi4cat/voc4cat_00000040con, + https://w3id.org/nfdi4cat/voc4cat_00000046con, + https://w3id.org/nfdi4cat/voc4cat_00000164con, + https://w3id.org/nfdi4cat/voc4cat_00000112con, + https://w3id.org/nfdi4cat/voc4cat_00000003con, + https://w3id.org/nfdi4cat/voc4cat_00000115con, + https://w3id.org/nfdi4cat/voc4cat_00000116con, + https://w3id.org/nfdi4cat/voc4cat_00000089con, + https://w3id.org/nfdi4cat/voc4cat_00000073con, + https://w3id.org/nfdi4cat/voc4cat_00000043con, + https://w3id.org/nfdi4cat/voc4cat_00000103con, + https://w3id.org/nfdi4cat/voc4cat_00000050con, + https://w3id.org/nfdi4cat/voc4cat_00000097con, + https://w3id.org/nfdi4cat/voc4cat_00000121con, + https://w3id.org/nfdi4cat/voc4cat_00000113con, + https://w3id.org/nfdi4cat/voc4cat_00000151con, + https://w3id.org/nfdi4cat/voc4cat_00000035con, + https://w3id.org/nfdi4cat/voc4cat_00000133con, + https://w3id.org/nfdi4cat/voc4cat_00000144con, + https://w3id.org/nfdi4cat/voc4cat_00000006con, + https://w3id.org/nfdi4cat/voc4cat_00000150con, + https://w3id.org/nfdi4cat/voc4cat_00000068con, + https://w3id.org/nfdi4cat/voc4cat_00000132con, + https://w3id.org/nfdi4cat/voc4cat_00000168con, + https://w3id.org/nfdi4cat/voc4cat_00000023con, + https://w3id.org/nfdi4cat/voc4cat_00000176con, + https://w3id.org/nfdi4cat/voc4cat_00000098con, + https://w3id.org/nfdi4cat/voc4cat_00000153con, + https://w3id.org/nfdi4cat/voc4cat_00000102con, + https://w3id.org/nfdi4cat/voc4cat_00000055con, + https://w3id.org/nfdi4cat/voc4cat_00000172con, + https://w3id.org/nfdi4cat/voc4cat_00000037con, + https://w3id.org/nfdi4cat/voc4cat_00000100con, + https://w3id.org/nfdi4cat/voc4cat_00000044con, + https://w3id.org/nfdi4cat/voc4cat_00000072con, + https://w3id.org/nfdi4cat/voc4cat_00000178con, + https://w3id.org/nfdi4cat/voc4cat_00000005con, + https://w3id.org/nfdi4cat/voc4cat_00000051con, + https://w3id.org/nfdi4cat/voc4cat_00000114con, + https://w3id.org/nfdi4cat/voc4cat_00000091con, + https://w3id.org/nfdi4cat/voc4cat_00000075con, + https://w3id.org/nfdi4cat/voc4cat_00000104con, + https://w3id.org/nfdi4cat/voc4cat_00000020con, + https://w3id.org/nfdi4cat/voc4cat_00000069con, + https://w3id.org/nfdi4cat/voc4cat_00000083con, + https://w3id.org/nfdi4cat/voc4cat_00000128con, + https://w3id.org/nfdi4cat/voc4cat_00000016con, + https://w3id.org/nfdi4cat/voc4cat_00000079con, + https://w3id.org/nfdi4cat/voc4cat_00000049con, + https://w3id.org/nfdi4cat/voc4cat_00000109con, + https://w3id.org/nfdi4cat/voc4cat_00000064con, + https://w3id.org/nfdi4cat/voc4cat_00000131con, + https://w3id.org/nfdi4cat/voc4cat_00000170con, + https://w3id.org/nfdi4cat/voc4cat_00000175con, + https://w3id.org/nfdi4cat/voc4cat_00000159con, + https://w3id.org/nfdi4cat/voc4cat_00000135con, + https://w3id.org/nfdi4cat/voc4cat_00000027con, + https://w3id.org/nfdi4cat/voc4cat_00000169con, + https://w3id.org/nfdi4cat/voc4cat_00000148con, + https://w3id.org/nfdi4cat/voc4cat_00000081con, + https://w3id.org/nfdi4cat/voc4cat_00000028con, + https://w3id.org/nfdi4cat/voc4cat_00000024con, + https://w3id.org/nfdi4cat/voc4cat_00000042con, + https://w3id.org/nfdi4cat/voc4cat_00000008con, + https://w3id.org/nfdi4cat/voc4cat_00000029con, + https://w3id.org/nfdi4cat/voc4cat_00000143con, + https://w3id.org/nfdi4cat/voc4cat_00000119con, + https://w3id.org/nfdi4cat/voc4cat_00000136con, + https://w3id.org/nfdi4cat/voc4cat_00000090con, + https://w3id.org/nfdi4cat/voc4cat_00000033con, + https://w3id.org/nfdi4cat/voc4cat_00000066con, + https://w3id.org/nfdi4cat/voc4cat_00000123con, + https://w3id.org/nfdi4cat/voc4cat_00000057con, + https://w3id.org/nfdi4cat/voc4cat_00000031con, + https://w3id.org/nfdi4cat/voc4cat_00000009con, + https://w3id.org/nfdi4cat/voc4cat_00000161con, + https://w3id.org/nfdi4cat/voc4cat_00000011con, + https://w3id.org/nfdi4cat/voc4cat_00000065con, + https://w3id.org/nfdi4cat/voc4cat_00000160con, + https://w3id.org/nfdi4cat/voc4cat_00000157con, + https://w3id.org/nfdi4cat/voc4cat_00000022con, + https://w3id.org/nfdi4cat/voc4cat_00000087con, + https://w3id.org/nfdi4cat/voc4cat_00000010con, + https://w3id.org/nfdi4cat/voc4cat_00000078con, + https://w3id.org/nfdi4cat/voc4cat_00000127con, + https://w3id.org/nfdi4cat/voc4cat_00000061con, + https://w3id.org/nfdi4cat/voc4cat_00000088con, + https://w3id.org/nfdi4cat/voc4cat_00000154con, + https://w3id.org/nfdi4cat/voc4cat_00000018con, + https://w3id.org/nfdi4cat/voc4cat_00000036con, + https://w3id.org/nfdi4cat/voc4cat_00000142con, + https://w3id.org/nfdi4cat/voc4cat_00000173con +
+
+
+
+

Concepts ↑

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photocatalysiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000001
Definition +

A process which catalyzes a chemical reaction through the absorption of sufficient light energy by a photocatalyst.


+
Narrower Concepts + photocatalytic processcon
+ photoreactor designcon
+ photocatalystcon
+ electronic statecon
+ photocatalytic experimentcon
+
+
+
+

photocatalystcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000002
Definition +

A material that absorbs photons (light) of appropriate energy and initiates or accelerates a photochemical reaction, while it regenerates itself after each reaction cycle.


+
Broader Concepts + photocatalysiscon
+
Narrower Concepts + synthesiscon
+ sample formcon
+ characterizationcon
+ semiconductorcon
+
+
+
+

semiconductorcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000003
Definition +

A material with electrical conductivity between that of a conductor and an insulator.


+
Broader Concepts + photocatalystcon
+
Narrower Concepts + categories of semiconductorscon
+ modification techniquecon
+ semiconductor propertycon
+
+
+
+

categories of semiconductorscon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000004
Definition +

Broad families of semiconduction materials (e.g., metal oxides) that can be used as photocatalysts in various applications.


+
Broader Concepts + semiconductorcon
+
Narrower Concepts + metal oxidecon
+
+
+
+

metal oxidecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000005
Definition +

A chemical compound formed by the reaction of a metal with oxygen.


+
Broader Concepts + categories of semiconductorscon
+
+
+
+

semiconductor propertycon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000006
Definition +

Characteristic properties of a semiconductor used in the field of photocatalysis. These properties determine its performance in the studied photocatalytic application.


+
Broader Concepts + semiconductorcon
+
Narrower Concepts + specific surface areacon
+ conduction bandcon
+ bandgap energycon
+ valence bandcon
+ pore size distributioncon
+ crystallinitycon
+ Fermi levelcon
+
+
+
+

Fermi levelcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000007
Definition +

The energy level in a semiconductor where the probability of finding an electron is 0.5.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

crystallinitycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000008
Definition +

The degree of a three-dimensional structural order of atoms which constitute the crystal lattice of a material.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

pore size distributioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000009
Definition +

Pore size distribution refers to the range of pore sizes in a material.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

bandgap energycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000010
Definition +

The energy difference between a semiconductor’s valence band top and conduction band bottom, which is required to excite an electron from the former to the latter.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

valence bandcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000011
Definition +

The band of energy levels in a solid fully occupied by electrons at 0 K (273.15 °C).


+
Broader Concepts + semiconductor propertycon
+
+
+
+

conduction bandcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000012
Definition +

The energy band of electronic levels of partially or fully filled mobile electrons in a metal or a semiconductor.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

specific surface areacon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000013
Definition +

Α measure of the total surface area of a material per unit mass or volume.


+
Broader Concepts + semiconductor propertycon
+
+
+
+

modification techniquecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000014
Definition +

Tecniques used to modify the properties of a photocatalyst, with the aim to increase its efficiency in a photocatalytic application.


+
Broader Concepts + semiconductorcon
+
Narrower Concepts + dopingcon
+
+
+
+

dopingcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000015
Definition +

The introduction of foreign atoms into a semiconductor leading to the formation of new energy levels and charge concentrations.


+
Broader Concepts + modification techniquecon
+
+
+
+

sample formcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000016
Definition +

The form in which the photocatalyst is introduced to the reaction chamber. This can include e.g., powders, pellets or thin films deposited on a substrate.


+
Broader Concepts + photocatalystcon
+
Narrower Concepts + powdered photocatalystcon
+ thin filmcon
+
+
+
+

powdered photocatalystcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000017
Definition +

A photocatalyst introduced to the reaction chamber in the form of a powder. Usually the powdered photocatalyst is spread inside a quartz / glass plate.


+
Broader Concepts + sample formcon
+
Narrower Concepts + powder masscon
+
+
+
+

powder masscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000018
Definition +

Mass of a powdered photocatalyst used for an experiment.


+
Broader Concepts + powdered photocatalystcon
+
+
+
+

thin filmcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000019
Definition +

A photocatalyst introduced to the reaction chamber in the form of a thin film. To form a thin film, a (powdered) photocatalyst is deposited on a substrate (e.g., glass or metal) using an appropriate deposition technique.


+
Broader Concepts + sample formcon
+
Narrower Concepts + deposition techniquecon
+ substratecon
+ deposited samplecon
+
+
+
+

deposition techniquecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000020
Definition +

A technique used to deposit (immobilize) a (powdered) photocatalyst on a substate. These techniques indlude (but are not limited to): doctor blading, spin coating, spray coating, etc.


+
Broader Concepts + thin filmcon
+
Narrower Concepts + spin coatingcon
+ spray coatingcon
+ doctor bladingcon
+
+
+
+

spray coatingcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000021
Definition +

A technique used to deposit uniform thin films onto a substrate by spraying a solution of the material onto the surface.


+
Broader Concepts + deposition techniquecon
+
+
+
+

doctor bladingcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000022
Definition +

A tape-casting method used to deposit thin films of a photocatalyst onto the surface of a substrate.


+
Broader Concepts + deposition techniquecon
+
+
+
+

spin coatingcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000023
Definition +

A technique used to deposit uniform thin films onto a substrate (e.g., metal or glass) by spinning at high speeds a solution (paste) of the material onto the surface.


+
Broader Concepts + deposition techniquecon
+
+
+
+

substratecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000024
Definition +

The substate onto which a (powdered) photocatalyst is deposited. Such substrates incude glass surfaces (e.g., borosilicate glass or conductive glass like ITO and FTO), ceramic substrates (e.g., alumina) or metal substrates (e.g., Ti foils, stainless steel etc.)


+
Broader Concepts + thin filmcon
+
Narrower Concepts + substrate materialcon
+ substrate dimensioncon
+
+
+
+

substrate materialcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000025
Definition +

The material that the substrate is made of. Common materials include: glass (conductive or not), ceramics and metal.


+
Broader Concepts + substratecon
+
Narrower Concepts + ceramic substratecon
+ metallic substratecon
+ glass substratecon
+
+
+
+

metallic substratecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000026
Definition +

A flat surface made of a metal (e.g., titanium, stainless steel) serving as a substrate for the deposition of a photocatalyst.


+
Broader Concepts + substrate materialcon
+
+
+
+

glass substratecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000027
Definition +

A flat surface made of glass serving as a substrate for the deposition of a photocatalyst.


+
Broader Concepts + substrate materialcon
+
Narrower Concepts + quartz glasscon
+ indium tin oxide coated glasscon
+ fluorine doped tin oxide coated glasscon
+ borosilicate glasscon
+
+
+
+

fluorine doped tin oxide coated glasscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000028
Definition +

Transparent conductive metal oxide (fluorine doped tin oxide) that can be used in the fabrication of transparent electrodes for thin films.


+
Broader Concepts + glass substratecon
+
+
+
+

indium tin oxide coated glasscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000029
Definition +

Transparent conductive metal oxide (indium tin oxide) that can be used in the fabrication of transparent electrodes for thin films.


+
Broader Concepts + glass substratecon
+
+
+
+

borosilicate glasscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000030
Definition +

A resistant to thermal shock type of glass, composed mainly of silica and boron trioxide.


+
Broader Concepts + glass substratecon
+
+
+
+

quartz glasscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000031
Definition +

A type of pure silicon dioxide, highly crystalline glass that allows the transmission of light in the UV wavelength range.


+
Broader Concepts + glass substratecon
+
+
+
+

ceramic substratecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000032
Definition +

A surface made of a ceramic material (e.g., alumina) serving as a substrate for the deposition of a photocatalyst.


+
Broader Concepts + substrate materialcon
+
+
+
+

substrate dimensioncon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000033
Definition +

The diamensions of the substrate.


+
Broader Concepts + substratecon
+
Narrower Concepts + substrate widthcon
+ substrate thicknesscon
+ substrate depthcon
+ substrate areacon
+
+
+
+

substrate widthcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000034
Definition +

The width of the substrate.


+
Broader Concepts + substrate dimensioncon
+
+
+
+

substrate depthcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000035
Definition +

The depth of the substrate.


+
Broader Concepts + substrate dimensioncon
+
+
+
+

substrate thicknesscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000036
Definition +

The thickness of the substrate.


+
Broader Concepts + substrate dimensioncon
+
+
+
+

substrate areacon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000037
Definition +

The surface area of the substrate.


+
Broader Concepts + substrate dimensioncon
+
+
+
+

deposited samplecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000038
Definition +

A thin film of the photocatalyst deposited on an appropiate for the application substrate.


+
Broader Concepts + thin filmcon
+
Narrower Concepts + thin film masscon
+ thin film dimensioncon
+
+
+
+

thin film masscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000039
Definition +

Mass of catalyst deposited onto the surface of a substrate.


+
Broader Concepts + deposited samplecon
+
+
+
+

thin film dimensioncon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000040
Definition +

The diamensions of the - deposited on the substrate - thin film


+
Broader Concepts + deposited samplecon
+
Narrower Concepts + thin film thicknesscon
+ thin film depthcon
+ thin film widthcon
+ thin film areacon
+
+
+
+

thin film widthcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000041
Definition +

The width of the film of the deposited photocatalyst.


+
Broader Concepts + thin film dimensioncon
+
+
+
+

thin film thicknesscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000042
Definition +

The thickness of the film of the deposited photocatalyst.


+
Broader Concepts + thin film dimensioncon
+
+
+
+

thin film depthcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000043
Definition +

The depth of the film of the deposited photocatalyst.


+
Broader Concepts + thin film dimensioncon
+
+
+
+

thin film areacon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000044
Definition +

The area of the substrate covered by the deposited photocatalyst.


+
Broader Concepts + thin film dimensioncon
+
+
+
+

synthesiscon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000045
Definition +

The process by which one or more chemical reactions are performed with the aim of converting a reactant or starting material into a product or multiple products.


+
Broader Concepts + photocatalystcon
+
Narrower Concepts + synthesis procedurecon
+ literature researchcon
+
+
+
+

literature researchcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000046
Definition +

Thorough search of available literature on the research topic of interest using online research platforms (e.g, Scopus, Google Scholar, Web of Science, Research Gate etc.) and / or libraries. Relevant literature can be found in the form of publications, books, abstracts and conference presentations.


+
Broader Concepts + synthesiscon
+
Narrower Concepts + literature collectioncon
+ literature organizationcon
+
+
+
+

literature collectioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000047
Definition +

Filtering of literature research to include only the most relevant sources of information for the application / experiment / catalysts of interest.


+
Broader Concepts + literature researchcon
+
+
+
+

literature organizationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000048
Definition +

Addition and organization of relevant literature of interest using a citation management software (e.g., Mendeley, Zotero, EndNote etc.) allowing for easy access and categorization.


+
Broader Concepts + literature researchcon
+
+
+
+

synthesis procedurecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000049
Definition +

Necessary steps needed to follow in order to reach the desired photocatalyst.


+
Broader Concepts + synthesiscon
+
Narrower Concepts + synthesis pressurecon
+ synthesis durationcon
+ synthesis equipmentcon
+ synthesis temperaturecon
+ chemical substance for synthesiscon
+ calcination stepcon
+ synthesis pHcon
+
+
+
+

synthesis durationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000050
Definition +

Duration of each synthesis step needed to synthesize the desired photocatalyst.


+
Broader Concepts + synthesis procedurecon
+
+
+
+

synthesis temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000051
Definition +

Temperature externally applied (if necessary) in any of the synthesis step. Higher temperature values can be observed if an exothermic reaction takes place during the synthesis.


+
Broader Concepts + synthesis procedurecon
+
+
+
+

synthesis pHcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000052
Definition +

pH value in each of the synthesis steps


+
Broader Concepts + synthesis procedurecon
+
+
+
+

synthesis pressurecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000053
Definition +

Pressure applied (if necessary) in any of the synthesis step. Changes in the pressure may be observed if variations in the temperature of the reaction occur (e.g., exothermic reaction)


+
Broader Concepts + synthesis procedurecon
+
+
+
+

calcination stepcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000054
Definition +

Heat treatment to reach the desired final photocatalyst. The parameters of the heat treatment can vary between each calcination step.


+
Broader Concepts + synthesis procedurecon
+
Narrower Concepts + calcination heating ratecon
+ calcination dwelling timecon
+ calcination initial temperaturecon
+ gaseous environment in calcinationcon
+ calcination final temperaturecon
+ gas flow rate in calcinationcon
+
+
+
+

gaseous environment in calcinationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000055
Definition +

A gas flow under which the calcination step takes place (e,g,, Ar or synthetic air)


+
Broader Concepts + calcination stepcon
+
+
+
+

gas flow rate in calcinationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000056
Definition +

The flow of gas (usually in ml min-1) used in the calcination steps during synthesis


+
Broader Concepts + calcination stepcon
+
+
+
+

calcination initial temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000057
Definition +

Initial temperature of the calcination step.


+
Broader Concepts + calcination stepcon
+
+
+
+

calcination final temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000058
Definition +

Final temperature of the calcination step.


+
Broader Concepts + calcination stepcon
+
+
+
+

calcination heating ratecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000059
Definition +

Rate of increasing or decreasing the temperature during the calcination step. Usually mentioned in K min-1.


+
Broader Concepts + calcination stepcon
+
+
+
+

calcination dwelling timecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000060
Definition +

Time (usually in h) for which a desired temperature is held.


+
Broader Concepts + calcination stepcon
+
+
+
+

synthesis equipmentcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000061
Definition +

Equipment used in each step of the synthesis of the photocatalysts. The equipment can incude (but not limited to): crucibles, pH meters, condensers, volumetric cylinders, centrifuges, test tubes, flasks, beakers, mechanical shakers, pipettes, syringes, magenetic stirrers, heating plates, fitlers, funnels and digital balances.


+
Broader Concepts + synthesis procedurecon
+
+
+
+

chemical substance for synthesiscon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000062
Definition +

Chemical substances used in the synthesis process of a desired photocatalyst.


+
Broader Concepts + synthesis procedurecon
+
Narrower Concepts + volume chemical substance for synthesiscon
+ mass of chemical substance for synthesiscon
+ concentration chemical substance for synthesiscon
+
+
+
+

mass of chemical substance for synthesiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000063
Definition +

Mass of chemicals used for synthesis


+
Broader Concepts + chemical substance for synthesiscon
+
+
+
+

volume chemical substance for synthesiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000064
Definition +

Volume of chemicals used for synthesis


+
Broader Concepts + chemical substance for synthesiscon
+
+
+
+

concentration chemical substance for synthesiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000065
Definition +

Concentration of chemicals used for synthesis


+
Broader Concepts + chemical substance for synthesiscon
+
+
+
+

characterizationcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000066
Definition +

A collection of techniques used to identify the (physico)chemical, morphological, structural, mechanical, optical and electrical properties of the syntesized photocatalysts. Characterization is performed after the synthesis of the photocatalysts to evaluate the success of the synthetic approach, but also after the completion of the evaluation of the materials in CO2 photoreduction to ensure their stability under the selected experimental parameters.


+
Broader Concepts + photocatalystcon
+
Narrower Concepts + scanning electron microscopycon
+ ultraviolet-visible spectroscopycon
+ photoluminescencecon
+ X-ray fluorescencecon
+ Raman spectroscopycon
+ thermogravimetric analysiscon
+ cyclic voltammetrycon
+ electron energy loss spectroscopycon
+ transmission electron microscopycon
+ fourier transform infrared spectroscopycon
+ nuclear magnetic resonance spectroscopycon
+ Mott-Schottky analysiscon
+ X-ray photoelectron spectroscopycon
+ atomic force microscopycon
+ Brunauer-Emmett-Teller surface area analysiscon
+ differential scanning calorimetrycon
+ X-ray diffractioncon
+
+
+
+

X-ray fluorescencecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000067
Definition +

A non-destructive analytical technique which uses a high-energy X-ray source to expose a material and monitors the emitted characteristic fluorescent X-Rays.


+
Broader Concepts + characterizationcon
+
+
+
+

electron energy loss spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000068
Definition +

An analytical technique used to measure the energy loss of electrons passing through a sample.


+
Broader Concepts + characterizationcon
+
+
+
+

Raman spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000069
Definition +

A spectroscopy technique studying the vibrational modes of molecules, by measuring the intensity and frequency of scattered by the sample of monochromatic light.


+
Broader Concepts + characterizationcon
+
+
+
+

atomic force microscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000070
Definition +

A high-resolution imaging technique that measures the interaction between a sharp probe and the sample’s surface to create a three-dimensional image of the surface’s morphology.


+
Broader Concepts + characterizationcon
+
+
+
+

differential scanning calorimetrycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000071
Definition +

A thermal analysis technique which compares the heat flow in a sample and a reference material under controlled applied temperature profiles.


+
Broader Concepts + characterizationcon
+
+
+
+

thermogravimetric analysiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000072
Definition +

A thermal analysis technique used to measure the change of a sample’s mass under the influence of controlled applied temperature profiles.


+
Broader Concepts + characterizationcon
+
+
+
+

nuclear magnetic resonance spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000073
Definition +

A spectroscopic technique that uses a static magnetic field and radiofrequency radiation to measure the magnetic resonance of atomic nuclei protons or electrons.


+
Broader Concepts + characterizationcon
+
+
+
+

photoluminescencecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000074
Definition +

Light emission of lower energy photons from a sample upon its photoexcitation.


+
Broader Concepts + characterizationcon
+
+
+
+

scanning electron microscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000075
Definition +

An electron microscopy technique that produces high-resolution images under high magnification of a sample's surface by assessing the secondary and back-scattered electrons produced by a focused electron beam.


+
Broader Concepts + characterizationcon
+
+
+
+

X-ray photoelectron spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000076
Definition +

A technique that analyzes the chemical composition of an X-ray irradiated sample by measuring the energies of the emitted electrons.


+
Broader Concepts + characterizationcon
+
+
+
+

X-ray diffractioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000077
Definition +

A technique which analyses the diffraction pattern produced when X-rays are scattered by a sample bombarded by a focused electron beam.


+
Broader Concepts + characterizationcon
+
+
+
+

transmission electron microscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000078
Definition +

Transmission electron microscopy is a technique that produces high-resolution images if the internal structure of a sample by using a beam of electrons to bombard the thin sample and measuring the intensity of the scattered transmitted electrons.


+
Broader Concepts + characterizationcon
+
+
+
+

ultraviolet-visible spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000079
Definition +

A technique used to measure the absorption, transmission or reflectance of light by a sample in the ultraviolet and visible regions of the electromagnetic spectrum.


+
Broader Concepts + characterizationcon
+
+
+
+

fourier transform infrared spectroscopycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000080
Definition +

A spectroscopic technique used to study the vibrational modes of chemical bonds of a sample using infrared radiation.


+
Broader Concepts + characterizationcon
+
+
+
+

Brunauer-Emmett-Teller surface area analysiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000081
Definition +

The study of physical adsorption of gas molecules on a solid surface for the calculation of the specific surface area of materials.


+
Broader Concepts + characterizationcon
+
+
+
+

cyclic voltammetrycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000082
Definition +

An electrochemical technique used to study the redox properties of a sample by measuring the current produced by an applied voltage sweep.


+
Broader Concepts + characterizationcon
+
+
+
+

Mott-Schottky analysiscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000083
Definition +

A method used in cyclic voltammetry to determine the charge carrier concentration and the flat-band potential of an electrochemical system by measuring the capacitance as a function of applied voltage.


+
Broader Concepts + characterizationcon
+
+
+
+

electronic statecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000084
Definition +

The energy state occupied by an electron in a photocatalyst. This state cab affect the electron's ability to participate in a photocatalytic reaction.


+
Broader Concepts + photocatalysiscon
+
Narrower Concepts + excited statecon
+ ground statecon
+
+
+
+

ground statecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000085
Definition +

Τhe lowest energy state of a system.


+
Broader Concepts + electronic statecon
+
+
+
+

excited statecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000086
Definition +

Τhe temporary state of a system with higher energy than its ground state caused by an external factor.


+
Broader Concepts + electronic statecon
+
+
+
+

photocatalytic processcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000087
Definition +

A multi-step process iniatiated by the absorption of photons by a photocatalyst. This process involves various sub-processes that include the photogeneration and transfer of electron and hole pairs.


+
Broader Concepts + photocatalysiscon
+
Narrower Concepts + photoexcitationcon
+ photoinduced electron transfercon
+ desorptioncon
+ charge recombinationcon
+ charge separationcon
+ oxidationcon
+ reductioncon
+ adsorptioncon
+ photoinduced charge generationcon
+ absorptioncon
+ photoinduced hole transfercon
+
+
+
+

photoinduced electron transfercon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000088
Definition +

The transfer of an electron initiated by the absorption of a photon of sufficient energy.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

photoinduced hole transfercon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000089
Definition +

The transfer of a hole initiated by the absorption of a photon of sufficient energy.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

photoinduced charge generationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000090
Definition +

The generation of electron - hole pairs in a semiconductor as a result of light absorption of sufficient energy to overcome the bandgap energy. Electrons (negative charge) get excited to the conduction band, while holes (positive charge) remain in the valence band.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

charge recombinationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000091
Definition +

The process by which photogenerated charges (electrons and holes) in a semiconductor recombine, resulting in the dissipation of energy in the form of e.g., heat or light.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

absorptioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000092
Definition +

Absorption is the process in which energy (e.g., photons) or an absorbent (e.g., a gas) is taken up by an absorbate.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

adsorptioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000093
Definition +

The binding (strong or weak) of a pollutant or a reactant molecule on the surface of a photocatalyst which facilitates the performance of photocatalytic reactions.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

desorptioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000094
Definition +

The process under which reactants, intermediates and products are released from the surface of the photocatalyst. Desoprtion can be faciliated by an increase in temparature or a change in the pH.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

charge separationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000095
Definition +

The process of separating positive and negative charges in a semiconductor, typically as a result of an external force, (e.g., photoexcitation).


+
Broader Concepts + photocatalytic processcon
+
+
+
+

photoexcitationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000096
Definition +

The state caused by the transition of electrons from the valence band top to the conduction band bottom by absorption of photons of sufficient energy.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

oxidationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000097
Definition +

The loss of electrons or an increase in the oxidation state of a species.


+
Broader Concepts + photocatalytic processcon
+
+
+
+

reductioncon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000098
Definition +

The gain of electrons or a decrease in the oxidation state of a species.


+
Broader Concepts + photocatalytic processcon
+
Narrower Concepts + photocatalytic CO2 reductioncon
+
+
+
+

photocatalytic CO2 reductioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000099
Definition +

The light-driven reduction (conversion) of carbon dioxide (CO2) to hydrocarbons and / or platform chemicals in presence of water. The absorption of light and the adsorption of the reactants is performed by a photocatalyst (usually a metal oxide).


+
Broader Concepts + reductioncon
+
+
+
+

photocatalytic experimentcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000100
Definition +

A lab-scale experiment performed to test the efficiency of a studied photocatalyst in a photocatalytic application (e.g., dye degradation, CO2 photoreduction e.t.c.).


+
Broader Concepts + photocatalysiscon
+
Narrower Concepts + sample pre-treatmentcon
+ evaluationcon
+ reactantcon
+ blank experimentcon
+ experiment durationcon
+ experiment temperaturecon
+ operation modecon
+ experiment pressurecon
+ experiment pressure dropcon
+
+
+
+

reactantcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000101
Definition +

The starting substances that undergo a chemical reaction to produce a desired product.


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + reactant puritycon
+ sacrificial reagantcon
+ reactant flow ratecon
+ reactant concentrationcon
+
+
+
+

reactant concentrationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000102
Definition +

Concentration of the reactants (e.g., CO2 and H2O) used in the photocatalytic CO2 reduction experiments


+
Broader Concepts + reactantcon
+
+
+
+

reactant puritycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000103
Definition +

Purity of reactants (e.g., CO2, H2O, He) used in the photocatalytic CO2 reduction experiments. Purity is measure of the impurities contained in the reactants' supply. The highest purity reactants should be used to ensure the collection of reliable results.


+
Broader Concepts + reactantcon
+
+
+
+

reactant flow ratecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000104
Definition +

The rate of flow of reactants (often in ml per min) in the photoreactor. Flow rates are usually controlled by mass flow controllers (MFCs)


+
Broader Concepts + reactantcon
+
+
+
+

sacrificial reagantcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000105
Definition +

Electron donors or hole scavengers used to reduce the recombination tendency of electrons and holes. Sacrificial reagents are used in photocatalysis to study an oxidation or reduction reaction seperately.


+
Broader Concepts + reactantcon
+
Narrower Concepts + sacrificial donorcon
+ sacrificial acceptorcon
+
+
+
+

sacrificial acceptorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000106
Definition +

A molecule that accepts electrons from photoexcited species in a redox reaction and is subsequently consumed or degraded.


+
Broader Concepts + sacrificial reagantcon
+
+
+
+

sacrificial donorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000107
Definition +

A molecule that donates electrons from photoexcited species in a redox reaction and is subsequently consumed or degraded.


+
Broader Concepts + sacrificial reagantcon
+
+
+
+

operation modecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000108
Definition +

Operation mode under the which the experiment takes place: batch of continuous flow mode.


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + batch modecon
+ flow modecon
+
+
+
+

flow modecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000109
Definition +

Under flow conditions, a continuous flow of reactants is supplied to the reaction chamber and the formed products are removed and identified by an appropriate technique.


+
Broader Concepts + operation modecon
+
+
+
+

batch modecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000110
Definition +

Operation mode in which the reaction chamber is filled with the (reactant) gas(es) up to a certain pressure, and the photoreaction products acummulate over time.


+
Broader Concepts + operation modecon
+
+
+
+

experiment durationcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000111
Definition +

The total duration of an experiment


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + irradiation durationcon
+ purging durationcon
+ sampling intervalcon
+
+
+
+

purging durationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000112
Definition +

Time for which a gas is purged through the reaction chamber.


+
Broader Concepts + experiment durationcon
+
+
+
+

sampling intervalcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000113
Definition +

The time in between the collection of two data points.


+
Broader Concepts + experiment durationcon
+
+
+
+

irradiation durationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000114
Definition +

The total duration in which the photocatalyst was under irradiation by the selected light source.


+
Broader Concepts + experiment durationcon
+
+
+
+

experiment temperaturecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000115
Definition +

The temperature (range) under which the photocatalytic reaction takes place.


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + experiment initial temperaturecon
+ experiment final temperaturecon
+
+
+
+

experiment initial temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000116
Definition +

The temperature at the initiaton of the experiment.


+
Broader Concepts + experiment temperaturecon
+
+
+
+

experiment final temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000117
Definition +

The temperature at the end of the experiment.


+
Broader Concepts + experiment temperaturecon
+
+
+
+

experiment pressurecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000118
Definition +

The pressure (range) under which the photocatalytic reaction takes place.


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + experiment final pressurecon
+ experiment initial pressurecon
+
+
+
+

experiment initial pressurecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000119
Definition +

The pressure at the initiaton of the experiment or before a sampling event.


+
Broader Concepts + experiment pressurecon
+
+
+
+

experiment final pressurecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000120
Definition +

The pressure at the end of the experiment or after a sampling event.


+
Broader Concepts + experiment pressurecon
+
+
+
+

experiment pressure dropcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000121
Definition +

The pressure drop occuring when collecting a gaseous sample for the reaction chamber. This pressure drop should be taken into consideration when caluclation the concentration of formed products.


+
Broader Concepts + photocatalytic experimentcon
+
+
+
+

sample pre-treatmentcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000122
Definition +

Pretreatment of the photocatalyst before its intoduction to the reaction chamber.


+
Broader Concepts + photocatalytic experimentcon
+
+
+
+

blank experimentcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000123
Definition +

Measurements performed to ensure that the studied photocatalytic reaction occurs because of the interaction of the photocatalyst with the reactants, and not from the environment or the photoreactor. Such blank experiment incude experiments under dark conditions, experiments with light but without a photocatalyst and experiments under light in the presence of the photocatalyst but without the targeted reactants.


+
Broader Concepts + photocatalytic experimentcon
+
+
+
+

evaluationcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000124
Definition +

Quantitative and qualitative evaluation of the outcome of a photocatalytic reaction (e.g., product formation from the photoreduction of CO2). The evaluation can lead to changes in the synthesis of the photocatalyst and / or selecting different experimental parameters.


+
Broader Concepts + photocatalytic experimentcon
+
Narrower Concepts + selectivitycon
+ apparent quantum yieldcon
+ product concentrationcon
+
+
+
+

selectivitycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000125
Definition +

In photocatalytic processes where product formation is expected, selectivity describes the ability of a photocatalyst to produce only the desired product with minimal (or none) of byproducts.


+
Broader Concepts + evaluationcon
+
+
+
+

apparent quantum yieldcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000126
Definition +

A measure of the efficiency of a photocatalytic reaction. It is expressed as the number of consumed charge carriers divided by the number of incident photons.


+
Broader Concepts + evaluationcon
+
+
+
+

product concentrationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000127
Definition +

The concentration (usually in ppm or mol) of the products formed during a photocatalytic reaction.


+
Broader Concepts + evaluationcon
+
+
+
+

photoreactor designcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000128
Definition +

Details describing the construction, physical dimensions, and operation of the photoreactor used to perform a photocatalytic reaction.


+
Broader Concepts + photocatalysiscon
+
Narrower Concepts + product identification methodcon
+ reaction chambercon
+ irradiation systemcon
+ gas feedcon
+ operation parameterscon
+
+
+
+

product identification methodcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000129
Definition +

Spectroscopic or chromatographic methods used to qualitatively and quantitatively identify the products of the photoreaction. Such devices are usually attached to the photoreactor, or a sample is being trasfered to an identification method via another medium (e.g., gastight syringes).


+
Broader Concepts + photoreactor designcon
+
Narrower Concepts + gas chromatographycon
+ liquid chromatographycon
+ mass spectrometrycon
+
+
+
+

gas chromatographycon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000130
Definition +

An analytical technique that separates and analyzes the components of a gas mixture by passing it though a stationary phase.


+
Broader Concepts + product identification methodcon
+
Narrower Concepts + gas chromatograph detectorcon
+ gas chromatograph calibrationcon
+ gas chromatograph sensitivitycon
+
+
+
+

gas chromatograph detectorcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000131
Definition +

Detectors of the gas chromatogragh used to identify the reaction products and intemediates.


+
Broader Concepts + gas chromatographycon
+
Narrower Concepts + dielectric-barrier discharge ionization detectorcon
+ thermal conductivity detectorcon
+ flame ionization detectorcon
+
+
+
+

flame ionization detectorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000132
Definition +

A type of gas chromatography detector that detects and quantifies the concentration of organic compounds in a gas sample emerging from a column, by measuring the electrical current generated by ionized gas constituents in a hydrogen flame.


+
Broader Concepts + gas chromatograph detectorcon
+
+
+
+

thermal conductivity detectorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000133
Definition +

A type of gas chromatography detector that measures the thermal conductivity of a gas sample and identifies its constituent molecules through changes in a filament’s temperature.


+
Broader Concepts + gas chromatograph detectorcon
+
+
+
+

dielectric-barrier discharge ionization detectorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000134
Definition +

Detector incorporating Ionization via a new dielectric barrier discharge He plasma.


+
Broader Concepts + gas chromatograph detectorcon
+
+
+
+

gas chromatograph sensitivitycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000135
Definition +

The minimum concentration of a product or intermediate that the gas chromatograph can identify.


+
Broader Concepts + gas chromatographycon
+
+
+
+

gas chromatograph calibrationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000136
Definition +

A process in which gaseous substances of known purity and concentration are introduced to the gas chromatograph and the respective area and retention time of the resulting peaks are identified. This process when concluded, allows for the calculation of concentrations of products and intermediates of the photoreaction.


+
Broader Concepts + gas chromatographycon
+
+
+
+

mass spectrometrycon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000137
Definition +

An analytical technique which determines the mass-to-charge ratio of ions in a sample to give information about the composition of the sample.


+
Broader Concepts + product identification methodcon
+
Narrower Concepts + mass spectrometer calibrationcon
+ mass spectrometer detectorcon
+ mass spectrometer sensitivitycon
+
+
+
+

mass spectrometer detectorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000138
Definition +

Detectors of the mass spectrometer used to identify the reaction products and intemediates.


+
Broader Concepts + mass spectrometrycon
+
+
+
+

mass spectrometer sensitivitycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000139
Definition +

The minimum concentration of a product or intermediate that the mass spectrometer can identify.


+
Broader Concepts + mass spectrometrycon
+
+
+
+

mass spectrometer calibrationcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000140
Definition +

A process in which gaseous substances of known purity and concentration are introduced to the mass spectrometer and the respective mass-to-charge ratios are identified. This process when concluded, allows for the calculation of concentrations of products and intermediates of the photoreaction.


+
Broader Concepts + mass spectrometrycon
+
+
+
+

liquid chromatographycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000141
Definition +

A sepation technique that uses a liquid mobile phase to separate the components of a mixture based on their interactions with a stationary phase and a mobile phase.


+
Broader Concepts + product identification methodcon
+
+
+
+

operation parameterscon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000142
Definition +

The range of critical for the safe operation of the photoreactor parameters.


+
Broader Concepts + photoreactor designcon
+
Narrower Concepts + operation pressurecon
+ operation temperaturecon
+
+
+
+

operation pressurecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000143
Definition +

Maximum and minimum of operation pressure range within the reactor can operate safely. Higher operation temperatures can lead to higher pressure values.


+
Broader Concepts + operation parameterscon
+
Narrower Concepts + pressure controller and monitorcon
+ maximum operation pressurecon
+ minimum operation pressurecon
+
+
+
+

maximum operation pressurecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000144
Definition +

Maximum of operation pressure range within the reactor can operate safely.


+
Broader Concepts + operation pressurecon
+
+
+
+

minimum operation pressurecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000145
Definition +

Minimum of operation pressure range within the reactor can operate safely.


+
Broader Concepts + operation pressurecon
+
+
+
+

pressure controller and monitorcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000146
Definition +

Equipment used for controlling and / or monitoring the pressure in various parts of a photoreactor. A vaccum pump is a typical example of such equipment.


+
Broader Concepts + operation pressurecon
+
Narrower Concepts + vacuum pumpcon
+
+
+
+

vacuum pumpcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000147
Definition +

Α mechanical device that removes gas molecules from a sealed chamber reaching pressures lower than the atmospheric pressure.


+
Broader Concepts + pressure controller and monitorcon
+
+
+
+

operation temperaturecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000148
Definition +

Maximum and minimum of operation temperature range within the reactor can operate safely.


+
Broader Concepts + operation parameterscon
+
Narrower Concepts + maximum operation temperaturecon
+ minimum operation temperaturecon
+ temperature controller and monitorcon
+
+
+
+

maximum operation temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000149
Definition +

Maximum of operation temperature range within the reactor can operate safely.


+
Broader Concepts + operation temperaturecon
+
+
+
+

minimum operation temperaturecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000150
Definition +

Minimum of operation temperature range within the reactor can operate safely.


+
Broader Concepts + operation temperaturecon
+
+
+
+

temperature controller and monitorcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000151
Definition +

Equipment used for controlling and/or monitoring the temperature in various parts of a photoreactor. This can include hot plates, heating elements and cryostats. Light sources in operation can also affect the temperature in the reaction chamber.


+
Broader Concepts + operation temperaturecon
+
+
+
+

reaction chambercon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000152
Definition +

A construction inside of which the photocatalyst and the reactants coexist and the photoreaction takes place.


+
Broader Concepts + photoreactor designcon
+
Narrower Concepts + reaction chamber volumecon
+ reaction chamber materialcon
+ reaction chamber shapecon
+ reaction chamber dimensioncon
+ optical windowcon
+
+
+
+

reaction chamber volumecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000153
Definition +

Volume of the reaction chamber, calculated by its dimensions. Volume of pipes and valves connected to the reaction chamber should also be calculated and added to the total volume.


+
Broader Concepts + reaction chambercon
+
+
+
+

reaction chamber dimensioncon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000154
Definition +

Height, width and depth (in cubic- or rectangular- shaped reaction chambers) or diameter and height (in cylindrer - shaped reaction chambers)


+
Broader Concepts + reaction chambercon
+
+
+
+

reaction chamber shapecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000155
Definition +

The shape of the reaction chamber. In gas-phase reactions, reaction chambers have usually a cylindrical, cubical or rectangular shape.


+
Broader Concepts + reaction chambercon
+
+
+
+

reaction chamber materialcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000156
Definition +

Material used for the construction of the main body of the reaction chamber.


+
Broader Concepts + reaction chambercon
+
+
+
+

optical windowcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000157
Definition +

A transparent material optimized to allow the transmission of electromagnetic radiation with low reflectance and scattering.


+
Broader Concepts + reaction chambercon
+
Narrower Concepts + optical window dimensionscon
+ optical window materialcon
+
+
+
+

optical window materialcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000158
Definition +

Material that the window is made of. The window, usually attached to the lid sealing the reaction chamber, allows for the incoming light to enter the reaction chamber and interact with the photocatalyst. The material of the window influences the wavelenth range the the photocatalyst experieneces.


+
Broader Concepts + optical windowcon
+
+
+
+

optical window dimensionscon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000159
Definition +

The dimension of the optical window (diameter / thickness) allowing the incoming light to enter the reaction chamber and interact with the photocatalyst.


+
Broader Concepts + optical windowcon
+
Narrower Concepts + optical window thicknesscon
+ optical window diametercon
+
+
+
+

optical window diametercon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000160
Definition +

Diameter of the optical window allowing the incoming light to enter the reaction chamber and interact with the photocatalyst.


+
Broader Concepts + optical window dimensionscon
+
+
+
+

optical window thicknesscon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000161
Definition +

Thickness of the optical window allowing the incoming light to enter the reaction chamber and interact with the photocatalyst.


+
Broader Concepts + optical window dimensionscon
+
+
+
+

gas feedcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000162
Definition +

Flow rates of gases used in an experiment. Gases can have either the role of a reactant (e.g., CO2) or be inert (e.g., Ar, He).


+
Broader Concepts + photoreactor designcon
+
Narrower Concepts + gas flow controller and monitorcon
+
+
+
+

gas flow controller and monitorcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000163
Definition +

Equipment used for controlling and / or monitoring the flow of gases (reactant or inert) needed for a photocatalytic experiment. Mass flow controllers (MFCs) are commonly used to controll gas flows.


+
Broader Concepts + gas feedcon
+
Narrower Concepts + mass flow controllercon
+
+
+
+

mass flow controllercon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000164
Definition +

Devices used to control and monitor gas or liquid flow rates.


+
Broader Concepts + gas flow controller and monitorcon
+
+
+
+

irradiation systemcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000165
Definition +

The irradiation system includes all the necessary equipment needed to perform a photocatalytic experiment. The system apart from the light source can include, filters, power units, lamp cooling devices etc.


+
Broader Concepts + photoreactor designcon
+
Narrower Concepts + light source propertycon
+ light sourcecon
+
+
+
+

light sourcecon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000166
Definition +

Light source used to irradiate a photocatalyst in a reaction chamber. These include sources with various intensities, powers and wavelength ranges, including Hg/Xe lamps, Xe lamps and LEDs.


+
Broader Concepts + irradiation systemcon
+
Narrower Concepts + light emitting diodecon
+ mercury-xenon lampcon
+ xenon lampcon
+
+
+
+

mercury-xenon lampcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000167
Definition +

A lamp containg a mixture of mercury (Hg) and xenon (Xe) gases. Under electric current, the gas mixture gets ionized through a discharge electric charge creating a plasma generating UV and visible light.


+
Broader Concepts + light sourcecon
+
+
+
+

xenon lampcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000168
Definition +

A lamp containg pure xenon (Xe) gas. Under electric current, the gas mixture gets ionized through a discharge electric charge creating a plasma generating UV and visible light.


+
Broader Concepts + light sourcecon
+
+
+
+

light emitting diodecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000169
Definition +

A solid-state semiconductor emitting light at highly controllable (narrow) wavelength ranges.


+
Broader Concepts + light sourcecon
+
+
+
+

light source propertycon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000170
Definition +

Specific of roperties of the light source dictaning its operation and its adequacy in the studied photocatalytic reaction.


+
Broader Concepts + irradiation systemcon
+
Narrower Concepts + light source distancecon
+ light operation currentcon
+ light intensitycon
+ light wavelengthcon
+ light power outputcon
+ light operation voltagecon
+
+
+
+

light source distancecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000171
Definition +

The distance of the light source from the reaction chamber and the photocatalyst.


+
Broader Concepts + light source propertycon
+
+
+
+

light operation currentcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000172
Definition +

The value of current (usually in A or mA) used to operate the selected light source.


+
Broader Concepts + light source propertycon
+
+
+
+

light operation voltagecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000173
Definition +

The value of voltage (usually in V or mV) used to operate the selected light source.


+
Broader Concepts + light source propertycon
+
+
+
+

light power outputcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000174
Definition +

The power of the light source (usually in W or mW). The power can be calculated by the multiplication of the current and voltage used to operate the light source,


+
Broader Concepts + light source propertycon
+
+
+
+

light intensitycon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000175
Definition +

The light intensity (usually in mW cm-2) of the selected light source. The light intensity should be measured at the same distance as the one between the light source and the reaction chamber / sample.


+
Broader Concepts + light source propertycon
+
+
+
+

light wavelengthcon

+ + + + + + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000176
Definition +

The distance between two successive peaks or troughs in a wave.


+
Broader Concepts + light source propertycon
+
Narrower Concepts + visiblecon
+ ultravioletcon
+ infraredcon
+
+
+
+

infraredcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000177
Definition +

Electromagnetic radiation with wavelengths typically in the range of 800 nm - 20000 nm.


+
Broader Concepts + light wavelengthcon
+
+
+
+

visiblecon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000178
Definition +

Electromagnetic radiation with wavelengths visible to the human eye, typically in the range of 400-800 nm.


+
Broader Concepts + light wavelengthcon
+
+
+
+

ultravioletcon

+ + + + + + + + + + + + + +
URIhttps://w3id.org/nfdi4cat/voc4cat_0000179
Definition +

Electromagnetic radiation with a wavelength typically in the range of 100-400 nanometers.


+
Broader Concepts + light wavelengthcon
+
+
+
+ +
+

Namespaces ↑

+
+
default (:)
+
https://w3id.org/nfdi4cat/voc4cat_
+
brick
+
https://brickschema.org/schema/Brick#
+
csvw
+
http://www.w3.org/ns/csvw#
+
dc
+
http://purl.org/dc/elements/1.1/
+
dcam
+
http://purl.org/dc/dcam/
+
dcat
+
http://www.w3.org/ns/dcat#
+
dcmitype
+
http://purl.org/dc/dcmitype/
+
dcterms
+
http://purl.org/dc/terms/
+
doap
+
http://usefulinc.com/ns/doap#
+
foaf
+
http://xmlns.com/foaf/0.1/
+
geo
+
http://www.opengis.net/ont/geosparql#
+
odrl
+
http://www.w3.org/ns/odrl/2/
+
org
+
http://www.w3.org/ns/org#
+
owl
+
http://www.w3.org/2002/07/owl#
+
prof
+
http://www.w3.org/ns/dx/prof/
+
prov
+
http://www.w3.org/ns/prov#
+
qb
+
http://purl.org/linked-data/cube#
+
rdf
+
http://www.w3.org/1999/02/22-rdf-syntax-ns#
+
rdfs
+
http://www.w3.org/2000/01/rdf-schema#
+
sdo
+
https://schema.org/
+
sh
+
http://www.w3.org/ns/shacl#
+
skos
+
http://www.w3.org/2004/02/skos/core#
+
sosa
+
http://www.w3.org/ns/sosa/
+
ssn
+
http://www.w3.org/ns/ssn/
+
time
+
http://www.w3.org/2006/time#
+
vann
+
http://purl.org/vocab/vann/
+
void
+
http://rdfs.org/ns/void#
+
wgs
+
https://www.w3.org/2003/01/geo/wgs84_pos#
+
xsd
+
http://www.w3.org/2001/XMLSchema#
+
+
+ +
+

Legend

+ + + +
colCollections
conConcepts
+
+ + \ No newline at end of file